Journal
HELIYON
Volume 8, Issue 11, Pages -Publisher
CELL PRESS
DOI: 10.1016/j.heliyon.2022.e11719
Keywords
CsGeI3 perovskite; ETL; HTL; ZnOS; CZTSe; Clean energy; SCAPS-1D
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In this study, an ultra-thin lead-free all-inorganic PV cell structure was optimized using SCAPS-1D simulator. The simulations showed that by optimizing the thickness and materials of each layer, higher power conversion efficiency could be achieved.
In this work, an ultra-thin (0.815 ??m) lead-free all-inorganic novel PV cell structure consisting of solid-state layers with the configuration SnO2/ZnOS/CsGeI3/CZTSe/Au has been optimized using SCAPS-1D simulator. ZnOS electron transport layer (ETL) has been deployed and various hole transport layer (HTL) material candidates have been considered to find the most suitable one in order to get the maximum possible power conversion efficiency (PCE). The simulation begins with the optimization of the thickness of the ZnOS buffer layer, followed by an analysis of HTL and ETL doping concentrations, thickness and bandgap optimization of absorber layer. The maximum permissible defect density at the ZnOS/CsGeI3 interface and the bulk defect density of the absorber layer (CsGeI3) are also investigated. It is also found that when the temperature rises, short circuit current density (Jsc) rises by 1.43 mA/K and open-circuit voltage (Voc) degrades by 2 mV/K. The optimized structure results in a PCE of 26.893% with Jsc, Voc, and fill factor (FF) of 28.172 mA cm-2, 1.0834 V, and 88.107% respectively. The cell performance parameters outperform those found in the recent literature. The simulated results of the proposed configuration are expected to be a helpful reference for the future implementation of a cost-effective and efficient all-inorganic perovskite PV cell.
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