☆ 4.7 Review

Integrated approaches for waste to biohydrogen using nanobiomediated towards low carbon bioeconomy

ADVANCED COMPOSITES AND HYBRID MATERIALS (2023)

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Article Energy & Fuels

Renewable hydrogen production by aqueous-phase reforming of Glycerol using Ni/Al2O3-MgO nano-catalyst: effect of the Ni loading

Farzad Bastan et al.

Summary: Aqueous-phase reforming (APR) of oxygenated hydrocarbons for hydrogen production has advantages in terms of feedstock availability and environmental benefits. In this study, Ni/Al2O3-MgO catalysts with different loadings were synthesized and tested for Glycerol APR reaction. The results showed that the catalyst with 5 wt% Ni loading demonstrated the highest catalytic activity, achieving a total conversion rate of 92% and a selectivity of 76% towards hydrogen production.

BIOMASS CONVERSION AND BIOREFINERY (2023)

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Article Chemistry, Applied

Hydrogen and value-added liquid fuel generation from pyrolysis-catalytic steam reforming conditions of microplastics waste dissolved in phenol over bifunctional Ni-Pt supported on Ti-Al nanocatalysts

Walid Nabgan et al.

Summary: This research explores the potential of using microplastics waste from oceans and soil as a source of liquid fuel, proposing pyrolysis with a catalyst as a solution. The introduction of a small portion of Pt metal in the nanocatalyst significantly improves its performance and stability. Valuable liquid products can be generated through the pyrolysis-catalytic steam reforming reaction. This study provides important insights into utilizing microplastics pollution for value-added fuel production and reducing threats to marine life.

CATALYSIS TODAY (2022)

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Article Engineering, Chemical

Non-oxidative conversion of real low density polyethylene waste into hydrogen and carbon nanomaterials over MgO supported bimetallic Co-Mo catalysts with different total Co-Mo contents

Ahmed M. Haggar et al.

Summary: A series of bimetallic CoMo/MgO catalysts with different total metal contents were prepared and used to convert LDPE waste into hydrogen and carbon nanomaterials. Increasing the CoMo content up to 40 wt% improved the catalytic activity and stability, achieving over 90% H-2 yield. The excessive formation of mixed oxide species enhanced the dispersion and stabilization of Co and Mo particles, leading to improved catalyst performance.

CHEMICAL ENGINEERING SCIENCE (2022)

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Article Chemistry, Physical

Nanofiber structured oxygen defective CoFe2O4-x catalyst for the water-gas shift reaction in waste- to-hydrogen processes

Yeol-Lim Lee et al.

Summary: Waste-to-hydrogen processes utilize the gasification of waste to produce hydrogen while reducing landfill/incineration. A nanofiber-structured CoFe(2)O(4) catalyst synthesized by electrospinning method showed superior redox property and exhibited the best catalytic activity in the water-gas shift reaction.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2022)

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Article Chemistry, Multidisciplinary

Hexagonal cerium oxide decorated on β-Ni(OH)2 nanosheets stabilized by reduced graphene oxide for effective sensing of H2O2

S. G. Manjushree et al.

Summary: The Ce-Ni(OH)(2)/rGO composite, with its unique two-dimensional hexagonal nanostructures, shows promising electrochemical performance for H2O2 sensing applications. The composite exhibits high sensitivity, selectivity, repeatability, and stability, making it a potential option for H2O2 sensing.

CARBON LETTERS (2022)

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Article Chemistry, Multidisciplinary

Preparation of ethanediamine-doped carbon quantum dots and their applications in white LEDs and fluorescent TLC plate

Wenya Wang et al.

Summary: In this study, a bottom-up approach was utilized to produce nitrogen-doped carbon quantum dots (N-CQDs) through hydrothermal treatment of microcrystalline cellulose with different nitrogen sources. Among these sources, Ethylenediamine (EDA) was found to yield N-CQDs with the highest fluorescence intensity and quantum yields. The fabricated N-CQDs are uniform spherical particles with excitation-dependent and long-wave emission properties, suitable for white LED light emission and fluorescent thin layer chromatography plate preparation.

CARBON LETTERS (2022)

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Article Chemistry, Physical

Hydrogen-Rich Gas Production from Two-Stage Catalytic Pyrolysis of Pine Sawdust with Calcined Dolomite

Tao Xu et al.

Summary: The catalytic pyrolysis of pine sawdust with calcined dolomite was investigated in this study, and the effects of temperature on product distribution and gas composition were evaluated. The results showed that increasing temperature led to higher gas yield but lower solid and liquid product yields. The calcined dolomite exhibited a significant catalytic effect, reducing tar production by 44% and increasing syngas yield by 52.9%.

CATALYSTS (2022)

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Article Chemistry, Physical

Oxygen evolution reaction at the Mo/W-doped bismuth vanadate surface: Assessing the dopant role by DFT calculations

Arianna Massaro et al.

Summary: The first-principles investigation of Mo/W-doped BiVO4 materials reveals the beneficial effect of Mo/W doping on surface re-organizations, forming a stabilizing Biopp site for hydration and catalytic capabilities, ultimately significantly enhancing catalytic performances for OER.

MOLECULAR CATALYSIS (2022)

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Article Chemistry, Physical

High temperature hydrothermal etching of g-C3N4 for synthesis of N doped carbon quantum dots-supported CdS photocatalyst to enhance visible light driven hydrogen generation

Zhenning Xu et al.

Summary: A facile method for synthesizing N-doped carbon quantum dots (NCQDs) was proposed, using g-C3N4 as the carbon-nitrogen source, and NCQDs-modified CdS nanocomposite catalysts for photocatalytic water splitting were successfully synthesized. The introduction of NCQDs into the composite catalysts not only enhanced the light absorption performance and suppressed carrier recombination, but also significantly improved the hydrogen production activity during photocatalytic water splitting under visible light.

MOLECULAR CATALYSIS (2022)

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Article Environmental Sciences

Temperature-dependent synthesis of multi-walled carbon nanotubes and hydrogen from plastic waste over A-site-deficient perovskite La0.8Ni1-xCoxO3-δ

Jingbo Jia et al.

Summary: Thermochemical conversion of plastic wastes into carbon nanotubes and hydrogen is a promising method. The catalyst design and reaction conditions play vital roles in the yields and morphologies of carbon nanotubes. Tuning of bimetallic nanoparticles as catalysts can enhance the efficiency. In this study, a catalyst precursor La0.8Ni1-xCoxO3-delta (LN1-xCx, x = 0.15, 0.5, 0.85) was developed to achieve in situ formation of bimetallic Ni-Co nanoparticles. The LN0.5C0.5 catalyst demonstrated the highest yields of multi-walled CNTs, attributed to its strong catalytic capability. The reaction temperature also influenced the morphology of carbon products.

CHEMOSPHERE (2022)

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A green and sensitive guanine-based DNA biosensor for idarubicin anticancer monitoring in biological samples: A simple and fast strategy for control of health quality in chemotherapy procedure confirmed by docking investigation

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Summary: Pt- and Pd-incorporated ZnO nanoparticles-decorated single-wall carbon nanotubes (Pt-Pd-ZnO/SWCNTs) nanocomposites were used to modify a glassy carbon electrode (GCE) for the detection of idarubicin. The morphology and structure of the nanocomposite were characterized using transmission electron microscopy (TEM) and field-emission scanning electron microscopy (FE-SEM) with energy-dispersive X-ray spectroscopy (EDS). The modified electrode, ds-DNA/Pt-Pd-ZnO/SWCNTs/GCE, was fabricated using a layer-by-layer modification technique and used as a voltammetric sensor for sensitive monitoring of idarubicin. The biosensor showed good performance in detecting idarubicin with a detection limit of 0.8 nM.

CHEMOSPHERE (2022)

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Nanocatalyzed upcycling of the plastic wastes for a circular economy

Changlong Wang et al.

Summary: Plastics are essential in our daily life, but they contribute to waste crisis and environmental pollution. The emergence of nanocatalyzed chemical upcycling of plastic waste offers a solution for converting waste to value-added chemicals and achieving a circular-plastics economy. This review provides a summary of plastic waste treatments and explores the chemical upcycling processes, emphasizing the role of coordination chemistry and the design of nanocatalysts.

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Article Environmental Sciences

Hydrothermal treatment of metal impregnated biomass for the generation of H2 and nanometal carbon hybrids

Ashutosh Kumar et al.

Summary: Impregnating Ru and Fe nanocatalysts has shown to enhance hydrogen yield in hydrothermal gasification of biomass, with sugarcane bagasse outperforming mosambi peels in H2 production at high temperatures. Additionally, Ru catalyst exhibited superior performance compared to Fe catalyst based on H2 and CH4 production.

ENVIRONMENTAL RESEARCH (2022)

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Article Environmental Sciences

Estimating the energy consumption function: evidence from across the globe

Muhammad Azam et al.

Summary: This study examines the factors determining the energy consumption function for 79 economies, based on the United Nations Sustainable Development Goals. The findings reveal that economic growth, carbon emissions, and urbanization are the key factors shaping energy consumption in most economies. Therefore, energy policies should take into account both economic growth and environmental quality to achieve sustainable development goals.

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Article Food Science & Technology

Recent advances in Ponceau dyes monitoring as food colorant substances by electrochemical sensors and developed procedures for their removal from real samples

Masoumeh Ghalkhani et al.

Summary: This study comprehensively reviews the properties, applications, chemistry, and toxicity of Ponceau dyes as food colorants. It discusses the electrochemical analysis of Ponceau dyes and the various methods used to remove these dyes.

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Article Energy & Fuels

Application of nanomaterials for enhanced production of biodiesel, biooil, biogas, bioethanol, and biohydrogen via lignocellulosic biomass transformation

Mehvish Mumtaz et al.

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FUEL (2022)

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AZ91 alloy nanocomposites reinforced with Mg-coated graphene: Phases distribution, interfacial microstructure, and property analysis

Zhanyong Zhao et al.

Summary: A new organic chemical reduction method was used to synthesize magnesium-coated graphene (GNPs) and fabricate nanocomposites with different contents. The microstructure of the composite was mainly composed of the matrix and the precipitated phase with different morphologies. With the increase of GNPs content, the grain and structure are refined, leading to improved hardness, reduced friction coefficient, and enhanced wear resistance.

JOURNAL OF ALLOYS AND COMPOUNDS (2022)

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Plasmonic origami: tuning optical properties by periodic folding of a gold nano film

S. Wang et al.

Summary: This study introduces a plasmonic metasurface with a rich dispersion spectrum and tunable absorption, which is promising for various photonic, light harvesting, and sensing applications.

JOURNAL OF THE OPTICAL SOCIETY OF AMERICA B-OPTICAL PHYSICS (2022)

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Review Chemistry, Multidisciplinary

Recent development of modified fluorescent carbon quantum dots-based fluorescence sensors for food quality assessment

Manash Jyoti Deka et al.

Summary: Food toxins are a significant health risk and can have serious consequences, including death. Carbon quantum dots, with their unique physical and chemical properties, are widely used in various fields, including food safety. They serve as fluorescence sensors for detecting pathogens and toxins in food and beverages, offering a low-cost, easy-to-use, and safe detection method.

CARBON LETTERS (2022)

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Article Chemistry, Physical

Hydrogen-Rich Gas Production from Two-Stage Catalytic Pyrolysis of Pine Sawdust with Nano-NiO/Al2O3 Catalyst

Tao Xu et al.

Summary: Hydrogen production from biomass pyrolysis is a promising and attractive technology. This study investigates the catalytic pyrolysis of pine sawdust using nano-NiO/Al2O3 catalyst, and observes the effects of residence time and catalytic temperature on the pyrolysis performance. The results show that longer residence times and higher catalytic temperatures can enhance gas production and improve the quality of the syngas.

CATALYSTS (2022)

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Article Chemistry, Physical

Facile synthesis of electrospun transition metallic nanofibrous mats with outstanding activity for ethylene glycol electro-oxidation in alkaline solution

R. M. Abdel Hameed et al.

Summary: In this study, a series of nickel-manganese alloy nanomaterials were prepared using the electrospinning technique and their electrochemical activity in the oxidation of ethylene glycol was investigated. The results showed that the electrochemical performance of the materials was significantly influenced by the manganese content, and the addition of 40 wt.% manganese resulted in the optimal oxidation current density and stability.

MOLECULAR CATALYSIS (2022)

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Article Nanoscience & Nanotechnology

Hydrothermal Microwave Synthesis of Co3O4/In2O3 Nanostructures for Photoelectrocatalytic Reduction of Cr(VI)

JieJie Nan et al.

Summary: Co3O4/In2O3 nanocomposites prepared via a microwave-hydrothermal method showed high efficiency and stability in reducing Cr(VI) through photoelectrocatalysis, with photo-generated electrons playing a key role and the p-n heterojunction significantly affecting the PEC performance.

ACS APPLIED NANO MATERIALS (2022)

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Article Engineering, Chemical

An efficient bifunctional Ni-Nb2O5 nanocatalysts for the hydrodeoxygenation of anisole

Juan Xu et al.

Summary: The Ni-Nb2O5 nanocatalysts prepared by the sol-gel method were investigated for their catalytic hydrodeoxy-genation (HDO) performance of anisole. The addition of Nb2O5 increased the acidity of the catalyst and promoted Ni dispersion, but a high niobium content resulted in the formation of an inactive Nb-Ni-O mixed phase. By adjusting the Nb/Ni molar ratio, the size and morphology of Ni grains in the catalysts were varied. Among the catalysts prepared at different Nb/Ni molar ratios, the Ni0.9Nb0.1 sample showed the largest surface area, mainly composed of spherical nanoparticles and crack pores. The Ni0.9Nb0.1 catalyst exhibited higher HDO performance for anisole and higher selectivity to cyclohexane compared to Ni catalysts. The selectivity of cyclohexane increased with the increase of reaction temperature, reaching almost complete conversion of anisole to cyclohexane at 240 degrees C, 3 MPa H-2, and 4 hours.

CHINESE JOURNAL OF CHEMICAL ENGINEERING (2022)

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Article Chemistry, Multidisciplinary

Nanochemistry approach for the fabrication of Fe and N co-decorated biomass-derived activated carbon frameworks: a promising oxygen reduction reaction electrocatalyst in neutral media

Hassan Karimi-Maleh et al.

Summary: This study successfully improved the performance of the oxygen reduction reaction (ORR) in neutral media by tailoring a biomass-derived ORR electrocatalyst. The iron- and nitrogen-doped activated carbon framework showed superior ORR activity and long-term stability. The catalyst also demonstrated lower onset potential and better resistance to sulfur poisoning compared to the traditional platinum-based catalyst, paving the way for the development of low-cost nanocatalysts.

JOURNAL OF NANOSTRUCTURE IN CHEMISTRY (2022)

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Article Chemistry, Physical

Effects of different Al2O3 support on HDPE gasification for enhanced hydrogen generation using Ni-based catalysts

Abid Farooq et al.

Summary: This study investigated the effects of Ni loading on different types of alumina for enhanced hydrogen generation during high-density polyethylene gasification. The results showed that the 13 nm-sized Al2O3 exhibited the highest catalytic activity among the alumina types. The use of Ni-loaded nm-sized alumina could be an excellent method for increased hydrogen production due to its higher Ni dispersion and surface area.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2021)

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Article Engineering, Environmental

Impact of temperature on the activity of Fe-Ni catalysts for pyrolysis and decomposition processing of plastic waste

Dingding Yao et al.

Summary: Thermal chemical processing is an efficient practice for handling plastic waste, with this study investigating the production of carbon materials through a pyrolysis followed by catalytic decomposition process. Results show that the yields of carbon and hydrogen gas are significantly proportional to the catalysis temperature, and low temperature leads to amorphous and disordered carbons while high temperature is necessary for carbon nanotube growth. FeNi1 catalyst at 800 degrees Celsius demonstrated higher activity in producing high quality carbon materials compared to FeNi2 catalyst.

CHEMICAL ENGINEERING JOURNAL (2021)

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Article Chemistry, Physical

Carbon nanotubes from post-consumer waste plastics: Investigations into catalyst metal and support material characteristics

Dingding Yao et al.

Summary: In this study, carbon nanotubes were produced from post-consumer mixed waste plastics using a pyrolysis-catalysis process, with the Ni-Fe/MCM41 catalyst displaying the highest catalytic activity. The order of catalytic activity was related to differences in catalyst pore volume and catalyst reducibility, with the formation of a Ni-Fe alloy suggested to be crucial for the promotion of carbon nanotube formation. By-product production of hydrogen at large quantities could be utilized as process fuel.

APPLIED CATALYSIS B-ENVIRONMENTAL (2021)

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Article Agricultural Engineering

Augmented biohydrogen production from rice mill wastewater through nano-metal oxides assisted dark fermentation

K. Rambabu et al.

Summary: This study demonstrates that the addition of NiO and CoO nanoparticles to dark fermentation of rice mill wastewater significantly enhances biohydrogen production. The optimal dosage of 1.5 mg/L for both NiO and CoO resulted in a 2.09-fold and 1.9-fold increase in biohydrogen yield, respectively.

BIORESOURCE TECHNOLOGY (2021)

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Article Engineering, Chemical

Effects of Graphene Oxide Nanosheets and Al2O3 Nanoparticles on CO2 Uptake in Semi-clathrate Hydrates

Hussein Hassan et al.

Summary: Gas hydrate/clathrate hydrate formation is an innovative method to trap CO2 into hydrate cages under appropriate thermodynamic and/or kinetic conditions. Nanoparticles, such as graphene oxide (GO) nanosheets and Al2O3 nanoparticles, can be utilized as effective kinetic promoters for hydrates of (CO2 + TBAB), resulting in increased storage capacity compared to TBAB aqueous solution systems.

CHEMICAL ENGINEERING & TECHNOLOGY (2021)

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Article Engineering, Chemical

Role of Carbon Capture, Storage, and Utilization to Enable a Net-Zero-CO2-Emissions Aviation Sector

Viola Becattini et al.

Summary: This study presents viable scenarios for the aviation industry to achieve net-zero CO2 emissions, with a focus on carbon capture and storage (CCS) and carbon capture and utilization (CCU). The research shows that point-source capture and storage of carbon is the most cost-effective solution, and it is already cost-competitive with business as usual (BAU) scenarios.

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2021)

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Article Chemistry, Physical

Plasma gasification of the medical waste

Altug Alp Erdogan et al.

Summary: The proper disposal of medical waste has become crucial in infection control in hospitals, especially during the Covid-19 pandemic. Utilizing gasification technologies to convert waste into energy is essential for sustainability and can help alleviate energy pressure.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2021)

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Article Chemistry, Analytical

Production of hydrogen and valuable fuels from polyethylene terephthalate waste dissolved in phenol reforming and cracking reactions via Ni-Co/CeO2 nano-catalyst

Walid Nabgan et al.

Summary: This research focuses on the preparation of Ni-Co/CeO2 catalysts using hydrothermal method for generating hydrogen and valuable fuels from PET waste liquefied in phenol. The catalyst prepared by the hydrothermal method exhibited higher activity, better stability, and reduced by-product formation.

JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS (2021)

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Review Energy & Fuels

Functional Materials for Waste-to-Energy Processes in Supercritical Water

Florentina Maxim et al.

Summary: Various organic wastes are used as reliable energy sources in supercritical water for energy recovery. Implementing SCW technologies on a large scale is a global interest, but issues related to materials stability and functionality still need to be addressed.

ENERGIES (2021)

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Carbon-Negative Hydrogen Production (HyBECCS) from Organic Waste Materials in Germany: How to Estimate Bioenergy and Greenhouse Gas Mitigation Potential

Johannes Full et al.

Summary: This paper discusses the potential and environmental benefits of biohydrogen production from biomass feedstock in Germany, presenting a methodological approach for evaluation and detailing a procedure for determining bioenergy potentials.

ENERGIES (2021)

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Article Green & Sustainable Science & Technology

Towards hydrogen production from waste activated sludge: Principles, challenges and perspectives

Qizi Fu et al.

Summary: Hydrogen production from waste activated sludge is a promising technology to recover energy from wastewater treatment plants, but there are challenges such as low organics utilization and rapid hydrogen consumption. Further research and solutions are needed to address these challenges and make the technology more feasible.

RENEWABLE & SUSTAINABLE ENERGY REVIEWS (2021)

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Review Chemistry, Physical

Hydrogen production from biomasses and wastes: A technological review

Muhammad Aziz et al.

Summary: Biomass and organic solid waste are promising alternative energy sources, with hydrogen being considered a clean and efficient secondary energy source. This study reviews various conversion routes and technologies for producing hydrogen from biomass and organic solid waste, highlighting both the progress and challenges in this field.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2021)

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Article Engineering, Multidisciplinary

Effect of two different fins (longitudinal-tree like) and hybrid nano-particles (MoS2 - TiO2) on solidification process in triplex latent heat thermal energy storage system

Kh Hosseinzadeh et al.

Summary: This study explores the use of a triplex-tube heat exchanger with hybrid nanoparticles to address the weak thermal conductivity of Phase Change Material (PCM) based storage units. Through Galerkin Finite Element Method (GFEM) analysis and experimental validation, it was found that the combined usage of nanoparticles and tree-like fins significantly reduces solidification time, with tree-like fins demonstrating the best performance.

ALEXANDRIA ENGINEERING JOURNAL (2021)

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Review Chemistry, Physical

Low-carbon production of iron and steel: Technology options, economic assessment, and policy

Zhiyuan Fan et al.

Summary: With the urgency to transition to a net-zero CO2 economy, governments and industries are focusing on decarbonizing hard-to-abate sectors like steel making. Current decarbonization technologies have limitations, and achieving deep decarbonization in the iron and steel industry will require a combination of factors including cost and technical maturity.

JOULE (2021)

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Review Biochemistry & Molecular Biology

Lignin-derived (nano)materials for environmental pollution remediation: Current challenges and future perspectives

Mohaddeseh Sajjadi et al.

Summary: The supply of affordable and clean drinking water is a crucial global environmental issue, and research is being done on utilizing biomass-derived biosorbents like lignin to remove contaminants effectively. Future efforts should focus on improving the economic viability of low-cost, green lignin-derived materials for broader applications in water treatment. Production of functionalized lignin and lignin-supported nanomaterials is a promising approach in nanotechnology for wastewater treatment.

INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES (2021)

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Article Chemistry, Physical

Promotion effect of rhenium on MoS2/ReS2@CdS nanostructures for photocatalytic hydrogen production

Tao Song et al.

Summary: The combination of ReS2 and MoS2 as cocatalysts for CdS photocatalyst facilitates efficient hydrogen production, with the introduction of a small amount of rhenium significantly enhancing the photocatalytic activity. The dual Z-scheme electron transfer pathway in MoS2/ReS2@CdS photocatalyst is attributed to the remarkable enhancement in photocatalytic performance.

MOLECULAR CATALYSIS (2021)

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Article Chemistry, Multidisciplinary

Growth of rGO nanostructures via facile wick and oil flame synthesis for environmental remediation

G. S. Lekshmi et al.

Summary: This study introduces an environmentally friendly and cost-effective method for large-scale production of high-quality rGO directly from used cooking sunflower oil. The produced graphene structures are effective in absorbing used commercial sunflower oil and engine oil, utilizing various adsorption mechanisms such as van der Waals forces and pi-pi stacking.

CARBON LETTERS (2021)

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Article Environmental Sciences

Catalytic upcycling of waste plastics over nanocellulose derived biochar catalyst for the coupling harvest of hydrogen and liquid fuels

Chenxi Wang et al.

Summary: A powerful biochar catalyst derived from nanocellulose was used for the first time to catalytically upcycle waste plastics into H-2 and liquid fuels. The results showed dominant aliphatics and aromatics in the liquid product, with the possibility of complete degradation of LDPE into liquid and gas without wax at specific conditions. Additionally, the catalyst favored increasing H-2 generation at the expense of light gas CnHm, especially CH4.

SCIENCE OF THE TOTAL ENVIRONMENT (2021)

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Review Chemistry, Physical

A compendium on metal organic framework materials and their derivatives as electrocatalyst for methanol oxidation reaction

Preetha Chandrasekharan Meenu et al.

Summary: Despite being a promising green energy generation technology, the effective application of direct methanol fuel cells is hindered by the lack of efficient, durable, and cost-effective catalysts for methanol oxidation. Metal organic frameworks and their derivatives have emerged as a promising area in electrocatalysts for this reaction, offering potential solutions to address the challenges in the effective application of this technology.

MOLECULAR CATALYSIS (2021)

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Review Biotechnology & Applied Microbiology

Sugarcane bagasse: a biomass sufficiently applied for improving global energy, environment and economic sustainability

E. O. Ajala et al.

Summary: Sugarcane bagasse, a biomass obtained from sugarcane processing, has been harnessed for various applications due to its abundance worldwide. Efficient pre-treatment methods such as alkaline and alkali-acid processes have been found to yield higher glucose production. The pre-treated sugarcane bagasse has shown susceptibility to acid and enzymatic hydrolysis, achieving over 80% glucose yield in both cases.

BIORESOURCES AND BIOPROCESSING (2021)

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Article Nanoscience & Nanotechnology

Advanced carbon materials with different spatial dimensions for supercapacitors

Xiaoliang Wu et al.

Summary: The study summarizes the main commercial electrode materials for supercapacitors as carbon materials, and the unique properties of carbon materials with different dimensions as electrode materials. It also discusses key issues for enhancing the electrochemical properties of carbon-based supercapacitors and the relationships among various influencing parameters.

NANO MATERIALS SCIENCE (2021)

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Review Chemistry, Multidisciplinary

Recent progress for silver nanowires conducting film for flexible electronics

Lu Zhang et al.

Summary: Conducting films based on silver nanowires (AgNWs) have various assembly methods, including printing, coating, vacuum filtration, template-assisted assembly, electrospinning, and gelating, each with its advantages.

JOURNAL OF NANOSTRUCTURE IN CHEMISTRY (2021)

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Article Nanoscience & Nanotechnology

Electrocatalytic and photocatalytic performance of noble metal doped monolayer MoS2 in the hydrogen evolution reaction: A first principles study

Zheng Zhang et al.

Summary: Noble metal doping can enhance the electrocatalytic performance of monolayer MoS2, but is unfavorable for its photocatalytic performance. The doping reduces the band gap, improves the electron transport performance, and lowers the activation energy for water splitting.

NANO MATERIALS SCIENCE (2021)

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Article Chemistry, Multidisciplinary

Eco-friendly graphene oxide-based magnesium oxide nanocomposite synthesis using fungal fermented by-products and gamma rays for outstanding antimicrobial, antioxidant, and anticancer activities

Rasha M. Fathy et al.

Summary: The study successfully synthesized magnesium oxide nanoparticles and graphene oxide based magnesium oxide nanocomposite using fungal fermented agricultural by-products and gamma irradiation. The nanoparticles exhibited excellent antioxidant, antimicrobial, and anticancer activities, demonstrating their potential for future applications.

JOURNAL OF NANOSTRUCTURE IN CHEMISTRY (2021)

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Article Chemistry, Multidisciplinary

A green and sustainable cellulosic-carbon-shielded Pd-MNP hybrid material for catalysis and energy storage applications

Vishal Kandathil et al.

Summary: A facile synthesis of cellulosic-carbon-shielded palladium-magnetic nanoparticle hybrid material (Pd-MNP@SCB) was demonstrated, showcasing its efficient performance in catalysis and energy storage applications with good recyclability and cycling stability.

JOURNAL OF NANOSTRUCTURE IN CHEMISTRY (2021)

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Article Chemistry, Multidisciplinary

Fabrication of surface-engineered superparamagnetic nanocomposites (Co/Fe/Mn) with biochar from groundnut waste residues for the elimination of copper and lead metal ions

Dhanya Vishnu et al.

Summary: This study utilized integrated magnetic nanoparticles and biochar to treat copper and lead pollutants in industrial wastewater, achieving enhanced adsorption and efficient removal. Analytical techniques demonstrated the excellent adsorption capacity and reaction characteristics of the nanoadsorbent.

JOURNAL OF NANOSTRUCTURE IN CHEMISTRY (2021)

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Article Chemistry, Physical

Subcritical and supercritical water in-situ gasification of metal (Ni/Ru/Fe) impregnated banana pseudo-stem for hydrogen rich fuel gas mixture

Ashutosh Kumar et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2020)

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Article Engineering, Chemical

The Role of Carbon Capture and Utilization, Carbon Capture and Storage, and Biomass to Enable a Net-Zero-CO2 Emissions Chemical Industry

Paolo Gabrielli et al.

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2020)

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Enhancement of hydrogen energy from Casuarina equisetifolia using NiO-Pr2O3/TiO2 and NiO/TiO2 nano composites

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INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2020)

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Article Chemistry, Physical

Conversion of polyethylene terephthalate plastic waste and phenol steam reforming to hydrogen and valuable liquid fuel: Synthesis effect of Ni-Co/ZrO2 nanostructured catalysts

Walid Nabgan et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2020)

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Article Biochemistry & Molecular Biology

Effect of nickel oxide nanoparticles on bioethanol production: Process optimization, kinetic and metabolic studies

Isaac A. Sanusi et al.

PROCESS BIOCHEMISTRY (2020)

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Review Green & Sustainable Science & Technology

Dark fermentative biohydrogen production from lignocellulosic biomass: Technological challenges and future prospects

Juliana Ferreira Soares et al.

RENEWABLE & SUSTAINABLE ENERGY REVIEWS (2020)

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Article Energy & Fuels

Pyrolysis and in-line catalytic decomposition of polypropylene to carbon nanomaterials and hydrogen over Fe- and Ni-based catalysts

Dingding Yao et al.

APPLIED ENERGY (2020)

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Article Engineering, Chemical

Biohydrogen Production via Dark Fermentation with Pig Manure and Glucose Using pH-Dependent Feeding

Tobias Weide et al.

CHEMICAL ENGINEERING & TECHNOLOGY (2020)

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Article Engineering, Environmental

Catalytic gasification of sewage sludge in near and supercritical water with different catalysts

Yunan Chen et al.

CHEMICAL ENGINEERING JOURNAL (2020)

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Article Chemistry, Physical

Promotion of bio oil, H2 gas from the pyrolysis of rice husk assisted with nano silver catalyst and utilization of bio oil blend in CI engine

R. Saravana Sathiya Prabhahar et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2020)

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Article Green & Sustainable Science & Technology

Seasonal energy storage for zero-emissions multi-energy systems via underground hydrogen storage

Paolo Gabrielli et al.

RENEWABLE & SUSTAINABLE ENERGY REVIEWS (2020)

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Article Chemistry, Multidisciplinary

Upgraded Valorization of Biowaste: Laser-Assisted Synthesis of Pd/Calcium Lignosulfonate Nanocomposite for Hydrogen Storage and Environmental Remediation

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` Development of Ni- and Fe- based catalysts with different metal particle sizes for the production of carbon nanotubes and hydrogen from thermo-chemical conversion of waste plastics

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Hydrogen production from supercritical water reforming of glycerol in an empty Inconel 625 reactor

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Quantum confinement controlled solar hydrogen production from hydrogen sulfide using a highly stable CdS0.5Se0.5/CdSe quantum dot-glass nanosystem

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Effect of Co Loading on the Activity and Selectivity of PtCo Aqueous Phase Reforming Catalysts

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Environmentally benign enhanced hydrogen production via lethal H2S under natural sunlight using hierarchical nanostructured bismuth sulfide

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RSC ADVANCES (2014)

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Architecture of rose and hollow marigold-like ZnIn2S4 flowers: structural, optical and photocatalytic study

Nilima S. Chaudhari et al.

RSC ADVANCES (2014)

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Article Energy & Fuels

Hydrogen rich gas production via nano-catalytic pyrolysis of bagasse in a dual bed reactor

Milad Hojjat Ansari et al.

JOURNAL OF NATURAL GAS SCIENCE AND ENGINEERING (2014)

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Article Chemistry, Physical

Catalytic reforming of activated sludge model compounds in supercritical water using nickel and ruthenium catalysts

Pooya Azadi et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2013)

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Study on the effect of metal types in (Me)-Al-MCM-41 on the mesoporous structure and catalytic behavior during the vapor-catalyzed co-pyrolysis of pubescens and LDPE

Wen-Wu Liu et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2013)

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Hydrogen production from catalytic supercritical water reforming of glycerol with cobalt-based catalysts

Thirasak Pairojpiriyakul et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2013)

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Article Chemistry, Physical

Air gasification of dried sewage sludge in a two-stage gasifier. Part 2: Calcined dolomite as a bed material and effect of moisture content of dried sewage sludge for the hydrogen production and tar removal

Tae-Young Mun et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2013)

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Investigations into the pyrolytic behaviour of birch wood and its main components: Primary degradation mechanisms, additivity and metallic salt effects

A. Khelfa et al.

JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS (2013)

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Bioenergy from forestry and changes in atmospheric CO2: Reconciling single stand and landscape level approaches

Francesco Cherubini et al.

JOURNAL OF ENVIRONMENTAL MANAGEMENT (2013)

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Investigation of Terahertz Vibration-Rotation Tunneling Spectra for the Water Octamer

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JOURNAL OF PHYSICAL CHEMISTRY A (2013)

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Nanostructured N-doped TiO2 marigold flowers for an efficient solar hydrogen production from H2S

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NANOSCALE (2013)

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Aqueous Phase Glycerol Reforming with Pt and PtMo Bimetallic Nanoparticle Catalysts: The Role of the Mo Promoter

Paul J. Dietrich et al.

TOPICS IN CATALYSIS (2013)

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Next generation biorefineries will solve the food, biofuels, and environmental trilemma in the energy-food-water nexus

Y. -H Percival Zhang

ENERGY SCIENCE & ENGINEERING (2013)

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Hydrogen production from cellulose, lignin, bark and model carbohydrates in supercritical water using nickel and ruthenium catalysts

Pooya Azadi et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2012)

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Top ten fundamental challenges of biomass pyrolysis for biofuels

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ENERGY & ENVIRONMENTAL SCIENCE (2012)

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Editorial Material Agronomy

Large-scale bioenergy from additional harvest of forest biomass is neither sustainable nor greenhouse gas neutral

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GLOBAL CHANGE BIOLOGY BIOENERGY (2012)

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Eco-friendly solar light driven hydrogen production from copious waste H2S and organic dye degradation by stable and efficient orthorhombic CdS quantum dots-GeO2 glass photocatalyst

Sanjay K. Apte et al.

GREEN CHEMISTRY (2012)

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Green methods for hydrogen production

Ibrahim Dincer

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2012)

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Hydrogen production through the aqueous phase reforming of ethylene glycol over supported Pt-based bimetallic catalysts

Ho-Dong Kim et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2012)

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Hydrogen production from glycerol by supercritical water gasification in a continuous flow tubular reactor

Simao Guo et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2012)

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Influence of impregnated metal on the pyrolysis conversion of biomass constituents

Francois-Xavier Collard et al.

JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS (2012)

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Aqueous Phase Glycerol Reforming by PtMo Bimetallic Nano-Particle Catalyst: Product Selectivity and Structural Characterization

Paul J. Dietrich et al.

TOPICS IN CATALYSIS (2012)

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H2 Production with Low CO Selectivity from Photocatalytic Reforming of Glucose on Ni/TiO2-SiO2

R. M. Mohamed et al.

CHINESE JOURNAL OF CATALYSIS (2012)

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Bio-hydrogen production based on catalytic reforming of volatiles generated by cellulose pyrolysis: An integrated process for ZrO reduction and zinc nanostructures fabrication

Adriana Veloso Maciel et al.

BIOMASS & BIOENERGY (2011)

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Nano-TiO2 Enhanced Photofermentative Hydrogen Produced from the Dark Fermentation Liquid of Waste Activated Sludge

Yuxiao Zhao et al.

ENVIRONMENTAL SCIENCE & TECHNOLOGY (2011)

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Ecofriendly hydrogen production from abundant hydrogen sulfide using solar light-driven hierarchical nanostructured ZnIn2S4 photocatalyst

Nilima S. Chaudhari et al.

GREEN CHEMISTRY (2011)

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Surfactant tunable hierarchical nanostructures of CdIn2S4 and their photohydrogen production under solar light

Ashwini Bhirud et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2011)

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Article Chemistry, Physical

Hydrogen production via CaO sorption enhanced anaerobic gasification of sawdust in a bubbling fluidized bed

Long Han et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2011)

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Hydrogen production by biomass gasification in supercritical water with bimetallic Ni-M/γAl2O3 catalysts (M = Cu, Co and Sn)

Sha Li et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2011)

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Article Chemistry, Physical

Self assembled CdLa2S4 hexagon flowers, nanoprisms and nanowires: novel photocatalysts for solar hydrogen production

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JOURNAL OF MATERIALS CHEMISTRY (2011)

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In situ generation of Ni metal nanoparticles as catalyst for H2-rich syngas production from biomass gasification

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APPLIED CATALYSIS A-GENERAL (2010)

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Aqueous phase reforming of glycerol for hydrogen production over Pt-Re supported on carbon

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APPLIED CATALYSIS B-ENVIRONMENTAL (2010)

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Catalytic gasification of glycerol in supercritical water

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CHEMICAL ENGINEERING JOURNAL (2010)

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Catalytic and Non-catalytic Supercritical Water Gasification of Microalgae and Glycerol

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INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2010)

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Hydrogen-rich gas production by air-steam gasification of rice husk using supported nano-NiO/γ-Al2O3 catalyst

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INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2010)

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Hydrogen production by biomass gasification in supercritical water over Ni/γAl2O3 and Ni/CeO2-γAl2O3 catalysts

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INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2010)

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Aqueous-phase reforming of ethylene glycol to hydrogen on Pd/Fe3O4 catalyst prepared by co-precipitation: Metal-support interaction and excellent intrinsic activity

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Nanorod alumina-supported Ni-Zr-Fe/Al2O3 catalysts for hydrogen production in auto-thermal reforming of ethanol

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MATERIALS RESEARCH BULLETIN (2010)

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RENEWABLE & SUSTAINABLE ENERGY REVIEWS (2010)

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Hydrogen production and performance of nickel based catalysts synthesized using supercritical fluids for the gasification of biomass

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APPLIED CATALYSIS B-ENVIRONMENTAL (2009)

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Development of a supported tri-metallic catalyst and evaluation of the catalytic activity in biomass steam gasification

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Hydrogen production from woody biomass over supported metal catalysts in supercritical water

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CATALYSIS TODAY (2009)

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Catalytic Gasification of Glucose over Ni/Activated Charcoal in Supercritical Water

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INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2009)

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Ni/CeO2/ZSM-5 catalysts for the production of hydrogen from the pyrolysis-gasification of polypropylene

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INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2009)

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Supercritical water gasification with Ni/ZrO2 catalyst for hydrogen production from model wastewater of polyethylene glycol

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Supercritical water gasification

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BIOFUELS BIOPRODUCTS & BIOREFINING-BIOFPR (2008)

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Visible light assisted highly efficient hydrogen production from H2S decomposition by CuGaO2 and CuGa1-xInxO2 delafossite oxides bearing nanostructured co-catalysts

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CATALYSIS COMMUNICATIONS (2008)

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Development of nano-NiO/Al2O3 catalyst to be used for tar removal in biomass gasification

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ENVIRONMENTAL SCIENCE & TECHNOLOGY (2008)

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Hydrogen production from glycerol by reforming in supercritical water over Ru/Al2O3 catalyst

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FUEL (2008)

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Cetyltrimethylammoniumbromide (CTAB)-assisted hydrothermal synthesis of ZnIn2S4 as an efficient visible-light-driven photocatalyst for hydrogen production

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INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2008)

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Visible light active pristine and Fe3+ doped CuGa2O4 spinel photocatalysts for solar hydrogen production

Karuppasamy Gurunathan et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2008)

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Dissociation of H2S under visible light irradiation (λ ≥ 420 nm) with FeGaO3 photocatalysts for the production of hydrogen

Esakkiappan Subramanian et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2008)

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Direct splitting of H2S into H2 and S on CdS-based photocatalyst under visible light irradiation

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JOURNAL OF CATALYSIS (2008)

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Photocatalytic splitting of H2S to produce hydrogen by gas-solid phase reaction

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CHINESE JOURNAL OF CATALYSIS (2008)

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Hydrogen production by biomass gasification in supercritical water: A systematic experimental and analytical study

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CATALYSIS TODAY (2007)

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Rose-red color oxynitride Nb2Zr6O17-xNx:: A visible light photocatalyst to hydrogen production

K. G. Kanade et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2007)

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Simultaneous hydrogen production and decomposition of H2S dissolved in alkaline water over CdS-TiO2 composite photocatalysts under visible light irradiation

Jum Suk Jang et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2007)

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Article Green & Sustainable Science & Technology

Thermodynamic analysis of a biomass anaerobic gasification process for hydrogen production with sufficient CaO

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RENEWABLE ENERGY (2007)

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Development of stable bimetallic catalysts for carbon dioxide reforming of methane

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Renewable energy policy and electricity market reforms in China

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ENERGY POLICY (2007)

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Pyrolysis of metal impregnated biomass: An innovative catalytic way to produce gas fuel

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JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS (2007)

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Confinement of nano CdS in designated glass: a novel functionality of quantum dot-glass nanosystems in solar hydrogen production

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JOURNAL OF MATERIALS CHEMISTRY (2007)

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Water gas shift reaction on Cu and Au nanoparticles supported on CeO2(111) and ZnO(000(1)over-bar): Intrinsic activity and importance of support interactions

Jose A. Rodriguez et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2007)

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Uniform dispersion of Ni nano particles in a carbon based catalyst for increasing catalytic activity for CH4 and H2 production by hydrothermal gasification

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FUEL (2006)

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Effect of supports and Ni crystal size on carbon formation and sintering during steam methane reforming

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APPLIED CATALYSIS A-GENERAL (2006)

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Review Chemistry, Multidisciplinary

Synthesis of transportation fuels from biomass: Chemistry, catalysts, and engineering

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CHEMICAL REVIEWS (2006)

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Fabrication of CdS/TiO2 nano-bulk composite photocatalysts for hydrogen production from aqueous H2S solution under visible light

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CHEMICAL PHYSICS LETTERS (2006)

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CdIn2S4 nanotubes and marigold nanostructures:: A visible-like photocatalyst

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Hydrogen production by biomass gasification in supercritical water: A parametric study

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INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2006)

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Effect of the nature of the support on the catalytic performance of noble metal catalysts for the water-gas shift reaction

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CATALYSIS TODAY (2006)

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Char-supported nano iron catalyst for water-gas-shift reaction - Hydrogen production from coal/biomass gasification

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PROCESS SAFETY AND ENVIRONMENTAL PROTECTION (2006)

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Aqueous-phase reforming of ethylene glycol over supported Pt and Pd bimetallic catalysts

GW Huber et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2006)

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Effect of water density on the gasification of lignin with magnesium oxide supported nickel catalysts in supercritical water

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INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2006)

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Supercritical water treatment of biomass for energy and material recovery

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COMBUSTION SCIENCE AND TECHNOLOGY (2006)

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An investigation into the catalytic cracking of LDPE using Py-GC/MS

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JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS (2005)

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Synthesis of a novel photocatalyst, ZnBiVO4, for the photodecomposition of H2S

BB Kale et al.

CANADIAN JOURNAL OF CHEMISTRY (2005)

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Hydrogen production from catalytic gasification of cellulose in supercritical water

XH Hao et al.

CHEMICAL ENGINEERING JOURNAL (2005)

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Review Chemistry, Physical

A review of catalytic issues and process conditions for renewable hydrogen and alkanes by aqueous-phase reforming of oxygenated hydrocarbons over supported metal catalysts

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APPLIED CATALYSIS B-ENVIRONMENTAL (2005)

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Review Agricultural Engineering

Biomass gasification in near- and super-critical water: Status and prospects

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BIOMASS & BIOENERGY (2005)

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Low-temperature catalytic gasification of lignin and cellulose with a ruthenium catalyst in supercritical water

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ENERGY & FUELS (2004)

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Review of current and future softwood kraft lignin process chemistry

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INDUSTRIAL CROPS AND PRODUCTS (2004)

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Effect of morphological characteristics of TiO2-supported noble metal catalysts on their activity for the water-gas shift reaction

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JOURNAL OF CATALYSIS (2004)

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Hydrogen-rich gas production from biomass catalytic gasification

PM Lv et al.

ENERGY & FUELS (2004)

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Aqueous-phase reforming of ethylene glycol over supported platinum catalysts

JW Shabaker et al.

CATALYSIS LETTERS (2003)

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Hydrogen from methane and supercritical water

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ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2003)

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Hydrogen from catalytic reforming of biomass-derived hydrocarbons in liquid water

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NATURE (2002)

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Ionic reactions and pyrolysis of glycerol as competing reaction pathways in near- and supercritical water

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JOURNAL OF SUPERCRITICAL FLUIDS (2002)

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Review of literature on catalysts for biomass gasification

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FUEL PROCESSING TECHNOLOGY (2001)

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Biomass gasification in supercritical water

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INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2000)

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Influence of the microscopic properties of the support on the catalytic activity of Au/ZnO, Au/ZrO2, Au/Fe2O3, Au/Fe2O3-ZnO, Au/Fe2O3-ZrO2 catalysts for the WGS reaction

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APPLIED CATALYSIS A-GENERAL (2000)

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