4.8 Article

Synthetic strategy for metallophthalocyanine covalent organic frameworks for electrochemical water oxidation

Related references

Note: Only part of the references are listed.
Review Chemistry, Multidisciplinary

Porous organic polymers for electrocatalysis

Dong-Hui Yang et al.

Summary: This paper provides a systematic overview of recent advances in the applications of porous organic polymers (POPs) as electrocatalysts in various reactions. The synthesis strategies, specific active sites, and catalytic mechanisms of POPs are summarized, and the current challenges and future directions in their electrocatalytic applications are discussed.

CHEMICAL SOCIETY REVIEWS (2022)

Article Chemistry, Physical

Direct and Linker-Exchange Alcohol-Assisted Hydrothermal Synthesis of Imide-Linked Covalent Organic Frameworks

Johannes Maschita et al.

Summary: Covalent organic frameworks (COFs) are a special type of porous materials, and a new environmentally friendly strategy - alcohol-assisted hydrothermal polymerization approach (aaHTP) can be used to synthesize stable and crystalline COFs, avoiding the use of toxic solvents.

CHEMISTRY OF MATERIALS (2022)

Article Energy & Fuels

Ni(II)-Based Coordination Polymer with Pi-Conjugated Organic Linker as Catalyst for Oxygen Evolution Reaction Activity

Trivender Kumar et al.

Summary: In this report, a new Ni(II)-based coordination polymer CP 1 was prepared by a solvothermal method, along with another CP denoted as CP 2, and utilized as oxygen evolution reaction (OER) catalysts in alkaline solution. The bi-linker CP 1 exhibited higher OER activity compared to the mono-linker CP 2, indicating the importance of the additional π-conjugated organic linker mesaconic acid in enhancing OER activity.

ENERGY & FUELS (2022)

Article Chemistry, Multidisciplinary

Quasi-Phthalocyanine Conjugated Covalent Organic Frameworks with Nitrogen-Coordinated Transition Metal Centers for High-Efficiency Electrocatalytic Ammonia Synthesis

Minghang Jiang et al.

Summary: The study presents a pyrolysis-free approach to incorporate ordered quasi-phthalocyanine N-coordinated transition metal centers into a 2D covalent organic framework for enhanced NRR performance. Among the Ti, Cu, and Co variants, Ti-COF exhibited superior NRR activity due to its ability to activate N-2 molecules and suppress HER. This work demonstrates the potential of 2D-COF materials with coordinated transition metal centers for efficient electrocatalytic NRR.

NANO LETTERS (2022)

Article Nanoscience & Nanotechnology

Deep Eutectic Solvent Synthesis of Perovskite Electrocatalysts for Water Oxidation

Sangki Hong et al.

Summary: This study reports a method for synthesizing La-based perovskites using an environmentally friendly solvent, resulting in perovskites with high electrocatalytic activity for water oxidation. Among the perovskites prepared, LaCoO3 exhibited the best electrocatalytic performance. These findings are important for the preparation of highly active perovskites for energy applications.

ACS APPLIED MATERIALS & INTERFACES (2022)

Article Chemistry, Physical

Interfacial electronic modulation by Fe2O3/NiFe-LDHs heterostructures for efficient oxygen evolution at high current density

Cheng-Fei Li et al.

Summary: In this study, flower-like nanosheets with Fe2O3/NiFe-layered double hydroxides (LDHs) heterointerfaces were fabricated, showing superior catalytic activity for OER at industrial grade current density. The research attributes the superior electrocatalytic performance to the optimized electronic configuration and promoted interfacial electron transfer of Fe2O3/NiFe-LDHs heterointerfaces.

APPLIED CATALYSIS B-ENVIRONMENTAL (2022)

Article Chemistry, Multidisciplinary

Stable Dioxin-Linked Metallophthalocyanine Covalent Organic Frameworks (COFs) as Photo-Coupled Electrocatalysts for CO2 Reduction

Meng Lu et al.

Summary: This study designed a series of stable metallophthalocyanine COFs as novel single-site catalysts with outstanding activity and selectivity for electrocatalytic CO2 reduction. Coupled with light, these COFs showed improved efficiency and potential for applications in the field of electrocatalysis.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Article Chemistry, Physical

Porphyrin-based NiFe Porous Organic Polymer Catalysts for the Oxygen Evolution Reaction

Jing Meng et al.

Summary: Porphyrin-based NiFe porous organic polymers (POPs) with good porosity and large BET surface areas have been synthesized. These bimetallic POPs exhibit excellent oxygen evolution reaction (OER) activity and show better catalytic performance than their monometallic counterparts, thanks to the synergistic interactions between iron and nickel centers.

CHEMCATCHEM (2021)

Article Chemistry, Multidisciplinary

Boosting the Electrocatalytic Conversion of Nitrogen to Ammonia on Metal-Phthalocyanine-Based Two-Dimensional Conjugated Covalent Organic Frameworks

Haixia Zhong et al.

Summary: By synthesizing metal-heteroatom-doped two-dimensional conjugated covalent organic frameworks (2D c-COFs), enhanced activity and selectivity of electrocatalytic NRR to ammonia have been achieved, making them among the best NRR electrocatalysts.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

Article Chemistry, Multidisciplinary

Stable Bimetallic Polyphthalocyanine Covalent Organic Frameworks as Superior Electrocatalysts

Yan Yue et al.

Summary: The study focuses on the development of highly stable bimetallic COFs for electrocatalytic CO2 reduction. The resulting CuPcF8-CoNPc-COF exhibits exceptional stability and electrocatalytic performance, with a faradaic efficiency of 97% and a turnover frequency of 2.87 s(-1).

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

Review Chemistry, Inorganic & Nuclear

Recent development on metal phthalocyanines based materials for energy conversion and storage applications

Anuj Kumar et al.

Summary: This article discusses the potential of using metal phthalocyanines (MPcs) as electrode materials to enhance the electrocatalytic activity of H-2, O-2, and CO2. It emphasizes the electronic and redox chemistry of phthalocyanines, as well as the potential applications of MPcs in energy conversion and storage devices, while also addressing challenges and future directions with MPcs-based materials.

COORDINATION CHEMISTRY REVIEWS (2021)

Article Chemistry, Multidisciplinary

Cost-effective catalysts for renewable hydrogen production via electrochemical water splitting: Recent advances

Zhijie Chen et al.

Summary: This review summarizes recent advances in low-cost electrocatalysts for water splitting, including transition metal-based and metal-free catalysts, focusing on catalyst design strategies and structure-performance mechanisms. The challenges and perspectives in this booming field are also presented.

CURRENT OPINION IN GREEN AND SUSTAINABLE CHEMISTRY (2021)

Article Chemistry, Multidisciplinary

Surface-Adsorbed Carboxylate Ligands on Layered Double Hydroxides/Metal-Organic Frameworks Promote the Electrocatalytic Oxygen Evolution Reaction

Cheng-Fei Li et al.

Summary: The study revealed the extraordinary role and mechanism of carboxylate ligands on bimetallic/tri-metallic layered double hydroxides/MOFs catalytic activity for the oxygen evolution reaction, enhancing the electrocatalytic performance of OER.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Article Chemistry, Physical

Conjugated nickel phthalocyanine polymer selectively catalyzes CO2-to-CO conversion in a wide operating potential window

Shuting Wei et al.

Summary: The utilization of intermittent renewable electricity for CO2 reduction requires high-performance catalysts with large current density and high selectivity for the target products. Ni phthalocyanine polymer demonstrates superior catalytic activity and high selectivity for CO2-to-CO conversion in a wide operating potential window, emphasizing the importance of modulating the structure and hydrophobicity of nanostructured catalysts for enhancing CO2RR performance.

APPLIED CATALYSIS B-ENVIRONMENTAL (2021)

Article Chemistry, Multidisciplinary

Two-Dimensional Covalent Organic Frameworks with Cobalt(II)-Phthalocyanine Sites for Efficient Electrocatalytic Carbon Dioxide Reduction

Bin Han et al.

Summary: The study presents the design and synthesis of two-dimensional polyimide-linked phthalocyanine COFs with stable properties, showing potential applications in electrocatalysis.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

Article Chemistry, Multidisciplinary

Conductive phthalocyanine-based metal-organic framework as a highly efficient electrocatalyst for carbon dioxide reduction reaction

Meng-Di Zhang et al.

Summary: The study achieved high CO Faradaic efficiency and large CO partial current density in CO2 electroreduction by constructing a two-dimensional metal-organic framework composed of nickel and phthalocyanine. Experimental results and DFT calculations confirmed that the Ni-N-4 units in the phthalocyanine ring are the catalytic active sites.

SCIENCE CHINA-CHEMISTRY (2021)

Article Chemistry, Physical

Bioinspired Precious-Metal-Free N4 Macrocycle as an Electrocatalyst for the Hydrogen Evolution Reaction

Sowmyashree Hadimane et al.

Summary: The synthesis of a novel HER catalyst CoTBImPc was presented, and experimental results demonstrated that CoTBImPc-CNT/GCE has higher activity and stability compared to traditional Pt/C catalyst and pristine metal phthalocyanine molecule.

ACS APPLIED ENERGY MATERIALS (2021)

Article Chemistry, Multidisciplinary

2D Salphen-based heteropore covalent organic frameworks for highly efficient electrocatalytic water oxidation

Lin-Lin Wang et al.

Summary: The study successfully constructed a series of 2D COFs with hexagonal and quadrilateral pores, and found that metallized salphen-based COFs can be used as electrocatalysts for water oxidation.

CHEMICAL COMMUNICATIONS (2021)

Article Chemistry, Multidisciplinary

Two-dimensional porphyrin covalent organic frameworks with tunable catalytic active sites for the oxygen reduction reaction

Jie-Yu Yue et al.

Summary: The ORR catalytic activity of four novel two-dimensional porphyrin COFs was tuned by changing the M atom in the center of the porphyrin backbone. The experimental structure-function relationship was consistent with density functional theory calculations based on the O-2-O-2*-OOH*-O*-OH*-OH- route.

CHEMICAL COMMUNICATIONS (2021)

Review Chemistry, Multidisciplinary

Recent advances in electrocatalysis with phthalocyanines

Shaoxuan Yang et al.

Summary: The applications of phthalocyanines (Pcs) in electrocatalysis have attracted attention due to their advantages of low cost, facile synthesis, and good chemical stability. Pcs offer high tailorability and structural diversity, making them promising for optimization in electrochemical devices and for various electrochemical reactions. Further research is needed to explore the structure-composition catalytic activity relationships of different Pc materials for future practical applications.

CHEMICAL SOCIETY REVIEWS (2021)

Review Chemistry, Physical

Pyrolysis-free covalent organic framework-based materials for efficient oxygen electrocatalysis

Xun Cui et al.

Summary: Pyrolysis-free covalent organic frameworks (COFs) serve as a promising platform for oxygen electrocatalysis research, enabling the preservation of active sites and facilitating a deeper understanding of electrocatalytic mechanisms. Their tunable porosity, atomically precise structures, and programmable topological architectures make them ideal candidates for high-performance electrocatalysts.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

Article Chemistry, Physical

Photo-assisted high performance single atom electrocatalysis of the N2 reduction reaction by a Mo-embedded covalent organic framework

Juan Wang et al.

Summary: This study introduces a Mo atom anchored covalent organic framework (MoPc-TFPN) for the photo-assisted electrocatalysis of N-2 reduction reaction, exhibiting low onset potential and effective suppression of competing reactions. Moreover, the catalyst possesses appropriate band edges and high light absorption efficiency, potentially enhancing the electrocatalytic efficiency of NRR.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

Review Chemistry, Multidisciplinary

Covalent organic frameworks (COFs) for electrochemical applications

Xiaojia Zhao et al.

Summary: This article introduces the application potential of covalent organic frameworks and discusses the design and synthesis strategies for their use in electrochemical applications. The focus is on the recent development of hybrid COF materials and COFs with hierarchical porosity which can address the challenges in electrochemical applications of COFs. Challenges and future trends in the use of COF materials in electrochemical applications are also outlined.

CHEMICAL SOCIETY REVIEWS (2021)

Article Green & Sustainable Science & Technology

Sustainable catalysts for water electrolysis: Selected strategies for reduction and replacement of platinum-group metals

L. M. Salonen et al.

Summary: Hydrogen is expected to be a key player in future clean energy technology, but its widespread application is hindered by the reliance on rare and expensive platinum-group metal catalysts. Research efforts are focused on reducing or replacing these Critical Raw Materials to overcome this bottleneck.

MATERIALS TODAY SUSTAINABILITY (2021)

Article Chemistry, Multidisciplinary

Intrinsic activity modulation and structural design of NiFe alloy catalysts for an efficient oxygen evolution reaction

Qiaoling Kang et al.

Summary: NiFe alloy catalysts are increasingly studied for their low cost and excellent OER catalytic activity, but the identification of active sites and OER mechanism remains controversial. This review discusses strategies to optimize active sites using amorphous structures and dual-metal single atoms, aiming to shed light on the exploration of novel electrocatalysts in the field of energy.

CHEMICAL SCIENCE (2021)

Review Chemistry, Multidisciplinary

Covalent organic framework-based materials for energy applications

De-Gao Wang et al.

Summary: Covalent organic frameworks (COFs) are emerging materials with flexible molecular design, high conjugated structures, and large surface area. They have shown promising perspectives in energy applications such as photocatalysis, electrocatalysis, and energy storage devices.

ENERGY & ENVIRONMENTAL SCIENCE (2021)

Article Nanoscience & Nanotechnology

Iron Phthalocyanine-Knitted Polymers as Electrocatalysts for the Oxygen Reduction Reaction

Antonio Valverde-Gonzalez et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

Article Chemistry, Multidisciplinary

Ionothermal Synthesis of Imide-Linked Covalent Organic Frameworks

Johannes Maschita et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Review Chemistry, Multidisciplinary

Advanced Electrocatalysts with Single-Metal-Atom Active Sites

Yuxuan Wang et al.

CHEMICAL REVIEWS (2020)

Article Chemistry, Inorganic & Nuclear

A Ni/Fe-based heterometallic phthalocyanine conjugated polymer for the oxygen evolution reaction

Dongdong Qi et al.

INORGANIC CHEMISTRY FRONTIERS (2020)

Article Chemistry, Multidisciplinary

Large-Scale, Bottom-Up Synthesis of Binary Metal-Organic Framework Nanosheets for Efficient Water Oxidation

Fei-Long Li et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Review Chemistry, Inorganic & Nuclear

Phthalocyanines for dye-sensitized solar cells

Maxence Urbani et al.

COORDINATION CHEMISTRY REVIEWS (2019)

Article Chemistry, Physical

Bimetal-phthalocyanine based covalent organic polymers for highly efficient oxygen electrode

Zhijian Liao et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2019)

Article Chemistry, Multidisciplinary

Molecular Evidence for the Catalytic Process of Cobalt Porphyrin Catalyzed Oxygen Evolution Reaction in Alkaline Solution

Xiang Wang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

Review Chemistry, Multidisciplinary

Heterogeneous single-atom catalysis

Aiqin Wang et al.

NATURE REVIEWS CHEMISTRY (2018)

Article Chemistry, Multidisciplinary

Activating lattice oxygen redox reactions in metal oxides to catalyse oxygen evolution

Alexis Grimaud et al.

NATURE CHEMISTRY (2017)

Article Chemistry, Physical

Cobalt-Modified Covalent Organic Framework as a Robust Water Oxidation Electrocatalyst

Harshitha Barike Aiyappa et al.

CHEMISTRY OF MATERIALS (2016)

Review Chemistry, Inorganic & Nuclear

PEM fuel cell electrocatalysts based on transition metal macrocyclic compounds

Yuyu Liu et al.

COORDINATION CHEMISTRY REVIEWS (2016)

Article Chemistry, Multidisciplinary

Bulk Synthesis of Exfoliated Two-Dimensional Polymers Using Hydrazone-Linked Covalent Organic Frameworks

David N. Bunck et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2013)

Article Chemistry, Multidisciplinary

Polyimides: Promising Energy-Storage Materials

Zhiping Song et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2010)

Article Chemistry, Physical

Phthalocyanines: structure and vibrations

DR Tackley et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2001)