4.8 Article

Smart L-borneol-loaded hierarchical hollow polymer nanospheres with antipollution and antibacterial capabilities

Journal

MATERIALS TODAY CHEMISTRY
Volume 26, Issue -, Pages -

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.mtchem.2022.101252

Keywords

Adsorption; Antimicrobial; Anti-pollutant; Hyper-crosslinked polymers; Porous polymer; Smart polymer

Funding

  1. Shanghai Sailing Program [21YF1431000]
  2. Open Research Fund Program of the State Key Laboratory of Molecular Engineering of Polymers (Fudan University) [K2022-40]
  3. National Research Foundation of Korea - Korean government (MSIT) [2021R1A2C2003685]

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A processible porous polymer with swellable hollow spherical morphology and branched L-borneol antibacterial agents was reported, which possesses high adsorption abilities and antibacterial performance. It can be prepared as a fine powder, anchored on membranes, processed into tablets, and assembled as a dye absorption device, showing notable potential as adsorbents for water purification and sewage treatment.
Porous organic polymers having well-defined morphologies and designable functionalities are poten-tially suitable materials for environmental remediation, e.g., for the removal of pollutants from water. However, single materials generally do not simultaneously possess high adsorption abilities and anti-bacterial performance, as well as easy processibility. Herein, we reported a processible porous polymer which composed swellable hollow spherical morphology and branched L-borneol antibacterial agents. These features endure a valuable capability of pollutant absorption for represented pollutants such as, organic dye (methylene blue), organic compound (bisphenol A), and the heavy metal (Cu2 thorn ). In addition, the L-borneol groups and 3D crosslinked hierarchical structure result in enhancement of antibacterial performance against Escherichia coli and Staphylococcus aureus. Moreover, we demonstrate the prepa-ration of the polymer as a fine powder could anchored on the membranes, processed into the tablet, adhered with the polyurethane foams, and assembled as the dye absorption device. The rationally designed polymers by this method show notable potential as adsorbents for water purification and sewage treatment.(c) 2022 Elsevier Ltd. All rights reserved.

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