A promoted charge separation/transfer and surface plasmon resonance effect synergistically enhanced photocatalytic performance in Cu nanoparticles and single-atom Cu supported attapulgite/polymer carbon nitride photocatalyst

The Cu nanoparticles and single-atom Cu-supported attapulgite/polymer carbon nitride (PCN) photo -catalyst was successfully synthesized via a calcination process. The C equivalent to N triple bond defect structure was successfully introduced into PCN structure through the composite process of modified attapulgite and PCN, suppressing the recombination of photogenerated electrons, narrowed the bandgap, and improved the efficiency of photocatalytic. The photoluminescence spectra, time-resolved fluorescence spectra, and ul-traviolet-visible diffuse reflectance spectra together with theoretical calculation revealed that the doping of single-atom Cu further promoted the separation of photogenerated carriers and reduced the bandgap. The surface plasmon resonance effect produced by Cu nanoparticles and the promoted charge separation and transfer effect of single-atom Cu synergistically enhance the photocatalytic performance, and the degra-dation rate toward methylene blue dye was 7.7 times higher than that of PCN. Compared with the traditional single-method modified PCN catalyst, the catalyst prepared by this cocktail-like multi-composite strategy has the characteristics of high charge separation efficiency, high catalytic efficiency, and high stability.(c) 2022 The Author(s). Published by Elsevier Ltd. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).

Automated summary

Cu nanoparticles and single-atom Cu-supported attapulgite/polymer carbon nitride (PCN) photocatalyst were successfully synthesized via calcination. The introduction of C equivalent to N triple bond defect structure into PCN suppressed electron recombination and improved photocatalytic efficiency. Doping of single-atom Cu further promoted carrier separation and reduced the bandgap. Synergistic effects of Cu nanoparticles and single-atom Cu enhanced photocatalytic performance, resulting in a degradation rate 7.7 times higher than PCN.