Flotation of copper oxide minerals: A review

Copper oxide minerals are important copper resources, which include malachite, azurite, chrysocolla, cuprite, etc. Flotation is the most widely used method for the enrichment of copper oxide minerals in the mineral processing industry. In this paper, the surface properties of copper oxide minerals and their effects on the mineral flotation behavior are systematically summarized. The flotation methods of copper oxide minerals and the interaction mechanism with reagents are reviewed in detail. Flotation methods include direct flotation (using chelating reagents or a fatty acid as collector), sulfidization flotation (using xanthate as collector), and activation flotation (using chelating reagents, ammonium/amine salts, metal ions, and oxidant for activation). An effective way to realize efficient flotation of copper oxide minerals is to increase active sites on the surface of copper oxide minerals to enhance the interaction of collector with the mineral surface. Besides, various perspectives for further investigation on the efficient recovery of copper oxide minerals are proposed.(c) 2022 Published by Elsevier B.V. on behalf of China University of Mining & Technology. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).

Automated summary

This paper summarizes the surface properties and flotation behavior of copper oxide minerals, and reviews the flotation methods and interaction mechanism with reagents. Increasing active sites on the surface of copper oxide minerals is an effective way to achieve efficient flotation. Various perspectives for further research are proposed.