Iridium-based electrocatalysts for the acidic oxygen evolution reaction: engineering strategies to enhance the activity and stability

Proton exchange membrane water electrolyzers (PEMWEs) for water electrolysis have received tremendous attention due to their immediate response, high proton conductivity, and low ohmic losses and gas crossover rate. The design of high-performance, economical and long-term durable electrocatalysts in an acidic environment is still the bottleneck to realize the large-scale commercialization of PEMWEs. Iridium-based materials represent one of the most promising classes of oxygen evolution reaction (OER) catalysts due to their intrinsic stability in acid media over ruthenium-based counterparts. However, only a few innovative approaches have been developed for synthesizing iridium-based catalysts (IBCs) in the past decade, possibly due to achieving high activity is detrimental to the stability of IBCs. Accordingly, various engineering strategies of optimizing IBCs have been proposed to address this issue, including doping engineering, morphology engineering, crystal phase engineering and support engineering. Herein, a critical overview focusing on different synthesis and modulation strategies of IBCs is presented, based on an in-depth understanding of the relationship between electronic structures, charge redistribution and activity as well as stability of the electrocatalysts. In addition, the unprecedented achievements in PEMWEs are summarized. The reaction mechanisms and future perspectives are critically discussed to inspire more rational design of IBCs toward practical applications.

Automated summary

Proton exchange membrane water electrolyzers (PEMWEs) have gained significant attention for their fast response, high proton conductivity, and low ohmic losses and gas crossover rate. However, developing high-performance and durable electrocatalysts in an acidic environment remains a challenge for the large-scale commercialization of PEMWEs. Iridium-based catalysts (IBCs) show promise for the oxygen evolution reaction (OER) due to their stability in acid media. This article provides a critical overview of different synthesis and modulation strategies of IBCs, considering their electronic structures, charge redistribution, activity, and stability. The achievements and future perspectives of PEMWEs are also discussed to inspire rational design of IBCs for practical applications.