4.6 Article

Novel Method for the Production of Titanium Foams to Reduce Stress Shielding in Implants

Journal

ACS OMEGA
Volume 8, Issue 2, Pages 1876-1884

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsomega.2c02340

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A novel method for preparing three-dimensional interconnected microporous titanium foams has been developed, in which a filler metal is inserted into titanium, followed by electrochemical dealloying for foam development. The developed foams showed interconnected porosity, and their mechanical and thermal properties were characterized. The developed titanium foams had elastic modulus close to human bones and higher yield strength, indicating potential for reducing stress shielding in orthopedic implants.
Titanium foams have potential applications in orthopedic and dental implants because of their low elastic modulus and good bone in-growth properties. In the present study, a novel method for the preparation of three-dimensional interconnected microporous titanium foams has been developed. This method is based on the insertion of a filler metal into the titanium metal by arc melting, followed by its removal by an electrochemical dealloying process for the development of foams. Complete removal of the filler metal by the electrochemical dealloying process was confirmed by an X-ray diffractometry (XRD) analysis, whereas scanning electron microscopy (SEM) analysis of the developed foams showed the development of interconnected porosity. Ti foams with different levels of porosities were successfully developed by varying the amount of the filler metal. Mechanical and thermal characterizations of the developed foams were carried out using compression testing and laser flash apparatus, respectively. The yield strength and elastic modulus of the developed foams were found to decrease by increasing the volume fraction of pores. The elastic modulus of the developed titanium foams (15.5-36 GPa) was found to be closer to that of human bones, whereas their yield strength (147-170 MPa) remained higher than that of human bones. It is therefore believed that the developed Ti foams can help in reducing the problem of stress shielding observed in orthopedic implants. The thermal diffusivity of the developed foams (4.3-0.69 mm(2)/s) was found to be very close to that of human dentine.

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