Fabrication of γ-Al2O3 Nanoarrays on Aluminum Foam Assisted by Hydroxide for Monolith Catalysts

Heat distribution and good adhesion of the washcoat on monolith catalysts are critical to improving catalytic activity and long-term stability. Compared with cordierite, metal foam presents a high thermal conductivity coefficient. Also, the availability of washcoat in situ grown on metal substrates opens the door to eliminating the problem of coating peeling. Generally, hydrothermal or thermal methods are used for the fabrication of in situ grown washcoat on metal substrates. In this research, the aluminum foam monolith vertically aligned Al2O3 nanowire array is successfully prepared at ambient temperature in an alkaline solution for the first time. Furthermore, the Pt-loaded Al2O3 nanowire array (0.5 gPt/Lmonolith) is applied to C2H4 degradation. The catalyst converts 90% C2H4 at 147 degrees C with a gas hourly space velocity (GHSV) of 20,000 h-1. And a little decrease (1%) is observed in catalytic activity, even in 15 vol % water vapors. The catalysts show good thermal stability and water resistance property over 36 h at 300 degrees C. Above all, this study presents a simple way of in situ growth of washcoat on metal-substrate monolith with potentially scaled manufacturing. And the monolith catalyst shows good catalytic performance on C2H4, which can be applied for volatile organic compound treatment.

Automated summary

Heat distribution and good adhesion of washcoat play a critical role in improving catalytic activity and stability. Metal foam exhibits a high thermal conductivity coefficient compared with cordierite, and the in situ grown washcoat on metal substrates eliminates the problem of coating peeling. This study successfully prepares an aluminum foam monolith with vertically aligned Al2O3 nanowire array at ambient temperature in alkaline solution, and the Pt-loaded Al2O3 nanowire array shows good catalytic performance on C2H4 degradation.