Journal
ACS EARTH AND SPACE CHEMISTRY
Volume 6, Issue 12, Pages 3101-3114Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsearthspacechem.2c00296
Keywords
hydrofluoroolefin; rate constant; atmospheric chemistry; Arrhenius parameters; structure-activity relationship
Funding
- Labex Voltaire [ANR-10-LABX-100-01]
- European Union [730997]
- Le Studium Loire Valley Institute for Advanced Studies
Ask authors/readers for more resources
Hydrofluoroolefins (HFOs) and related haloalkenes are a family of compounds with various industrial applications. The primary sink for these chemicals in the atmosphere is the gas-phase electrophilic addition of OH to the olefinic bond. This study investigates the structure-activity relationships (SARs) and predicts temperature-dependent OH reaction rate coefficients for HFOs, providing useful information for assessing their environmental impact.
Hydrofluoroolefins (HFOs) and related haloalkenes are a family of compounds, primarily man-made, with many industrial applications. Gas-phase electrophilic addition of OH to the olefinic bond represents the primary sink for these chemicals in the atmosphere. The degree and type of halogenation strongly affect their chemical reactivity, leading to differing reactivities with the OH radical that have presented a challenge for structure-activity relationships (SARs). Here, we investigate and extend the SARs to estimate temperature-dependent OH reaction rate coefficients, k(T), at tropospheric temperatures. We considered two techniques: the group-additivity approach of Atkinson and coworkers and the recent method of Tokuhashi and co-workers; we found the latter to make superior predictions for halogenated olefins. We extended Tokuhashi et al.'s SAR to include more olefins and to predict temperature dependencies. We compared SAR predictions against new absolute k(T) for two HFOs (3,3,3-trifluoropropene and 1,1,3,3-tetrafluoropropene) measured using the pulsed-laser photolysis-laser-induced fluorescence technique from 212 to 373 K. The Arrhenius expressions were determined as k(OH+CF3CH=CH2)(T) = (8.86 +/- 0.82) x 10(-13) exp[(159 +/- 26)/T] and k(OH+CF2HCH=CF2)(T) = (7.46 +/- 0.34) x 10(-13) exp[(365 +/- 12)/T]. The measured k(T) was predicted accurately between 200 and 400 K using the modified Tokuhashi approach. Our new measurements of the OH reaction rate coefficient with 3,3,3-trifluoropropene were in excellent agreement with literature determinations. We represent the first reported k(T) for 1,1,3,3-tetrafluoropropene. Given that new HFOs enter the market frequently, such estimation techniques may be a helpful screening tool for assessing their environmental impact before they are examined further and reach the mass-production phase.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available