Don't become your own resting state

Article Chemistry, Multidisciplinary

Selective and quantitative functionalization of unprotected a-amino acids using a recyclable

Aitor Bermejo-Lopez et al.

Summary: A new Ir(III)-NHC catalyst with remarkable activity and selectivity in the N-alkylation of unprotected amino acids has been reported, allowing the synthesis of a wide range of unprotected nonnatural amino acids. The method also enables the synthesis of amino-acid-based surfactants with high yields and catalyst recyclability.

CHEM (2022)

Add to Collection

Article Chemistry, Multidisciplinary

Selective Synthesis of Imines by Photo-Oxidative Amine Cross-Condensation Catalyzed by PCN-222(Pd)

Aitor Bermejo-Lopez et al.

Summary: Palladium-metalated PCN-222 catalyzes the aerobic photo-oxidative cross-condensation of anilines with benzylic amines to produce a series of imines, including intermediate compounds like 2-(benzylideneamino)-aniline and 2-(benzylideneamino)phenols. The recyclability studies demonstrate excellent activity and selectivity even after five runs, showcasing the potential of this methodology for synthetic applications, such as the synthesis of the antitumor agent PMX-610.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2021)

Add to Collection

Article Chemistry, Multidisciplinary

Iron-Catalyzed Cross-Coupling of Propargyl Ethers with Grignard Reagents for the Synthesis of Functionalized Allenes and Allenols

Daniels Posevins et al.

Summary: An iron-catalyzed cross-coupling reaction of propargyl ethers with Grignard reagents was disclosed, allowing for efficient chirality transfer and preparation of various fluoroalkyl allenes. Additionally, an iron-catalyzed cross-coupling of Grignard reagents with alpha-alkynyl oxetanes and tetrahydrofurans was demonstrated as a straightforward approach towards fully substituted beta- or gamma-allenols.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Add to Collection

Article Chemistry, Multidisciplinary

Nonclassical Mechanism in the Cyclodehydration of Diols Catalyzed by a Bifunctional Iridium Complex

Greco Gonzalez Miera et al.

CHEMISTRY-A EUROPEAN JOURNAL (2019)

Add to Collection

Don't become your own resting state

Related references

Selective and quantitative functionalization of unprotected a-amino acids using a recyclable

Selective Synthesis of Imines by Photo-Oxidative Amine Cross-Condensation Catalyzed by PCN-222(Pd)

Iron-Catalyzed Cross-Coupling of Propargyl Ethers with Grignard Reagents for the Synthesis of Functionalized Allenes and Allenols

Nonclassical Mechanism in the Cyclodehydration of Diols Catalyzed by a Bifunctional Iridium Complex

Export Citation

Share Paper