Journal
CHEMISTRYSELECT
Volume 7, Issue 43, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/slct.202202905
Keywords
ATRP; polyacrylamide; DOPO; block copolymer
Categories
Funding
- Basic Scientific Research Special Fund of Education Department of Heilongjiang Province [135509301]
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In this paper, polyacrylamide with reactive group bromine (PAM-Br) was synthesized by the ATRP method, and DOPO was organically modified to obtain acrylate monomers with DOPO functional groups (DOPOAA). PAM-b-DOPOAA block copolymers with controllable molecular mass and narrow molecular mass distribution were obtained using a mixture of water and N, N-dimethylformamide (DMF) as the solvent. The study is of great importance in terms of its potential applications and scientific significance.
Polyacrylamide has been a hot topic of research in recent years, however, the preparation of block copolymers of polyacrylamide using ATRP method has been little studied. In this paper, polyacrylamide with reactive group bromine (PAM-Br) was synthesized by atom transfer radical polymerization (ATRP) using acrylamide (AM) as the monomer and water as the solvent, and polyacrylamide was used as the macromolecular initiator for the next reaction step. Then 9,10-dihydro-9-oxa-10-phosphafi-10-oxide (DOPO) was organically modified to obtain acrylate monomers with DOPO functional groups (DOPOAA), and a mixture of water and N, N-dimethylformamide (DMF) was used as the solvent to obtain PAM-b-DOPOAA block copolymers with controllable molecular mass and narrow molecular mass distribution. The effects of the molecular mass of the macromolecular initiator, polymerization time, and the molar ratio of catalyst to the ligand on the polymerization process were investigated. The structure and properties of the products were also characterized by H-1-NMR, FTIR, XPS, DSC, TG, etc. The PAM-b-DOPOAA prepared by ATRP method can artificially design the length and ratio of the two chain segments, realizing one additive with two functions and the permanent existence of the function of polymer additives.
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