4.6 Review

Electrochemical organic reactions: A tutorial review

Journal

FRONTIERS IN CHEMISTRY
Volume 10, Issue -, Pages -

Publisher

FRONTIERS MEDIA SA
DOI: 10.3389/fchem.2022.956502

Keywords

electrocatalysis; organic reaction; CO2 reduction; kinetics; electrochemical techniques and methods

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While electrochemistry involves basic oxidation and reduction reactions, it becomes more complicated in real organic electrochemical reactions. The principles used in electrochemical reactions have been derived from physical organic chemistry and have influenced other organic/inorganic reactions. This review focuses on two main themes: the optimization factors in electrochemical reactions including electrodes, supporting electrolytes, and cell design, and the studies conducted in this field over the past 10 years. Electrochemical reactions can serve as a versatile tool for synthesizing important reactions by modifying the constant electrolysis current.
Although the core of electrochemistry involves simple oxidation and reduction reactions, it can be complicated in real electrochemical organic reactions. The principles used in electrochemical reactions have been derived using physical organic chemistry, which drives other organic/inorganic reactions. This review mainly comprises two themes: the first discusses the factors that help optimize an electrochemical reaction, including electrodes, supporting electrolytes, and electrochemical cell design, and the second outlines studies conducted in the field over a period of 10 years. Electrochemical reactions can be used as a versatile tool for synthetically important reactions by modifying the constant electrolysis current.

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