4.7 Article

Diacetyliminoxyl as a selective radical reagent for organic synthesis: dehydrogenation and dehydrogenative C-O coupling reactions

Related references

Note: Only part of the references are listed.
Review Chemistry, Multidisciplinary

Conjugated nitroxides

Evgeny Tretyakov et al.

Summary: In recent years, research on organic paramagnetic compounds has focused on their applied aspects. One of the key trends in this field is the study of conjugated nitroxides, which have specific features that make them important in various applications. This review discusses the achievements, physicochemical properties, magneto structural correlations, and practical applications of conjugated nitroxides.

RUSSIAN CHEMICAL REVIEWS (2022)

Article Chemistry, Organic

Hidden Reactivity of Barbituric and Meldrum's Acids: Atom-Efficient Free-Radical C-O Coupling with N -Hydroxy Compounds

Igor B. Krylov et al.

Summary: The reactivity of CH-acidic and structurally related enol-containing heterocycles towards N-oxyl radicals was investigated, showing high affinity between these substrates. Highly selective and efficient N-oxyl radical mediated C-O coupling of substituted barbituric or Meldrum's acids with N-hydroxy compounds was achieved using inexpensive manganese-containing salts as oxidants. Metal-free C-O coupling was demonstrated using diacetyliminoxyl as both the oxidant and the coupling partner.

SYNTHESIS-STUTTGART (2022)

Review Chemistry, Applied

Photochemical and Electrochemical Strategies towards Benzylic C-H Functionalization: A Recent Update

Monica Oliva et al.

Summary: This review discusses recent advances in benzylic C-H functionalization using organic radical strategies involving photochemistry and electrochemistry as sustainable tools. The potential and prospects of this field are highlighted, along with mechanistic details of typical reactions to aid researchers in exploring new discoveries and opportunities.

ADVANCED SYNTHESIS & CATALYSIS (2021)

Article Chemistry, Organic

Stable and reactive diacetyliminoxyl radical in oxidative C-O coupling with β-dicarbonyl compounds and their complexes

Alexander S. Budnikov et al.

Summary: In this study, the unusually stable diacetyliminoxyl radical was introduced as a novel reagent for oxidative C-O coupling, striking a balance between transient and stable unreactive radicals. Additionally, the catalytic activity of acids, bases, and transition metal ions in free-radical coupling was revealed using this model radical.

ORGANIC & BIOMOLECULAR CHEMISTRY (2021)

Review Chemistry, Inorganic & Nuclear

Coordination Chemistry of Nitronyl Nitroxide Radicals Has Memory

Dominique Luneau

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (2020)

Review Chemistry, Organic

Oxime radicals: generation, properties and application in organic synthesis

Igor B. Krylov et al.

BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY (2020)

Article Chemistry, Multidisciplinary

Toward Improved Performance of All-Organic Nitroxide Radical Batteries with Ionic Liquids: A Theoretical Perspective

Luke Wylie et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2019)

Article Chemistry, Applied

Cross-Dehygrogenative C-O Coupling of Oximes with Acetonitrile, Ketones and Esters

Zhen-Yu Chen et al.

ADVANCED SYNTHESIS & CATALYSIS (2019)

Article Chemistry, Multidisciplinary

Triplet Fullerenes as Prospective Spin Labels for Nanoscale Distance Measurements by Pulsed Dipolar EPR Spectroscopy

Olesya A. Krumkacheva et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Article Chemistry, Multidisciplinary

A Platform of Phenol-Based Nitroxide Radicals as an EPR Toolbox in Supramolecular and Click Chemistry

Till Hauenschild et al.

CHEMPLUSCHEM (2019)

Article Nanoscience & Nanotechnology

New Spin on Organic Radical Batteries-An Isoindoline Nitroxide-Based High-Voltage Cathode Material

Kai-Anders Hansen et al.

ACS APPLIED MATERIALS & INTERFACES (2018)

Article Chemistry, Multidisciplinary

Coordination-Initiated Nitroxide-Mediated Polymerization (CI-NMP)

Gerard Audran et al.

AUSTRALIAN JOURNAL OF CHEMISTRY (2018)

Review Chemistry, Multidisciplinary

Advances in the synthesis of nitroxide radicals for use in biomolecule spin labelling

Marius M. Haugland et al.

CHEMICAL SOCIETY REVIEWS (2018)

Review Chemistry, Multidisciplinary

Nitroxide Radicals with Cucurbit[n]urils and Other Cavitands

Olivier Ouari et al.

ISRAEL JOURNAL OF CHEMISTRY (2018)

Review Polymer Science

Nitroxide radical polymers - a versatile material class for high-tech applications

Kai-Anders Hansen et al.

POLYMER CHEMISTRY (2018)

Review Chemistry, Multidisciplinary

Imidazoline and imidazolidine nitroxides as controlling agents in nitroxide-mediated pseudoliving radical polymerization

Mariya V. Edeleva et al.

RUSSIAN CHEMICAL REVIEWS (2018)

Article Chemistry, Multidisciplinary

Light-Induced Spin Transitions in Copper-Nitroxide-Based Switchable Molecular Magnets: Insights from Periodic DFT plus U Calculations

Rocio Sanchez-de-Armas et al.

CHEMISTRY-A EUROPEAN JOURNAL (2018)

Article Biochemistry & Molecular Biology

Nitroxide Spin-Labelling and Its Role in Elucidating Cuproprotein Structure and Function

Christopher E. Jones et al.

CELL BIOCHEMISTRY AND BIOPHYSICS (2017)

Article Chemistry, Inorganic & Nuclear

Light-Induced Spin State Switching and Relaxation in Spin Pairs of Copper(II)-Nitroxide Based Molecular Magnets

Sergey V. Tumanov et al.

INORGANIC CHEMISTRY (2017)

Article Chemistry, Physical

Light-Induced Spin State Switching in Copper(II)-Nitroxide-Based Molecular Magnet at Room Temperature

Xu Dong et al.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2017)

Article Chemistry, Physical

Landscape of the structure-O-H bond dissociation energy relationship of oximes and hydroxylamines

Rina Dao et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2017)

Review Chemistry, Multidisciplinary

Electrochemical Alcohol Oxidation Mediated by TEMPOlike Nitroxyl Radicals

Rosaria Ciriminna et al.

CHEMISTRYOPEN (2017)

Article Chemistry, Inorganic & Nuclear

Spin-state-correlated optical properties of copper(II)-nitroxide based molecular magnets

Irina Yu. Barskaya et al.

DALTON TRANSACTIONS (2017)

Article Chemistry, Multidisciplinary

Transition-Metal Catalyst Free Oxidative Radical Arylation of N-Methylpyrrole

Esma Kocaoglu et al.

ACS OMEGA (2017)

Review Chemistry, Multidisciplinary

Polymer-Based Organic Batteries

Simon Muench et al.

CHEMICAL REVIEWS (2016)

Article Biochemistry & Molecular Biology

Complementary-addressed site-directed spin labeling of long natural RNAs

Elena S. Babaylova et al.

NUCLEIC ACIDS RESEARCH (2016)

Article Polymer Science

Trityl-based alkoxyamines as NMP controllers and spin-labels

Gerard Audran et al.

POLYMER CHEMISTRY (2016)

Article Chemistry, Organic

Oxidative C-O coupling of benzylmalononitrile with 3-(hydroxyimino)pentane-2,4-dione

I. B. Krylov et al.

RUSSIAN JOURNAL OF ORGANIC CHEMISTRY (2015)

Article Chemistry, Multidisciplinary

Ultrafast Photoswitching in a Copper-Nitroxide-Based Molecular Magnet

Wawrzyniec Kaszub et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2014)

Article Chemistry, Multidisciplinary

Aerobic oxidation catalysis with stable radicals

Qun Cao et al.

CHEMICAL COMMUNICATIONS (2014)

Review Chemistry, Multidisciplinary

Scavenging of Organic C-Centered Radicals by Nitroxides

Elena G. Bagryanskaya et al.

CHEMICAL REVIEWS (2014)

Review Chemistry, Multidisciplinary

The chemistry of nitroxide radicals in the molecular design of magnets

E. V. Tretyakov et al.

RUSSIAN CHEMICAL REVIEWS (2009)

Article Chemistry, Multidisciplinary

The first crystal structure of a monomeric phenoxyl radical: 2,4,6-tri-tert-butylphenoxyl radical

Virginia W. Manner et al.

CHEMICAL COMMUNICATIONS (2008)

Article Electrochemistry

Organic radical battery: nitroxide polymers as a cathode-active material

H Nishide et al.

ELECTROCHIMICA ACTA (2004)