Journal
INORGANIC CHEMISTRY FRONTIERS
Volume 10, Issue 1, Pages 201-210Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2qi01949c
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Funding
- NSFC
- [21971241]
- [21871050]
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We propose a rigid-flexible synergistic strategy for the syntheses of ferrocene-functionalized indium-based metal-organic frameworks (In-MOFs) through introducing rigid carboxylic acids as auxiliary ligands. The large cations are used to induce flexible 1,1 '-ferrocene dicarboxylic acid (H(2)FcDCA) in a controllable coordination mode to construct target frameworks. A series of In-MOFs based on the H(2)FcDCA ligand have been successfully synthesized using this strategy. The introduction of rigid OX2- ligands and large cation template leads to the syntheses of various In-MOFs with good third order nonlinear optical properties and redox activity.
We propose a rigid-flexible synergistic strategy for the syntheses of ferrocene-functionalized indium-based metal-organic frameworks (In-MOFs) through introducing rigid carboxylic acids as auxiliary ligands, where the large cations are used to induce flexible 1,1 '-ferrocene dicarboxylic acid (H(2)FcDCA) in a controllable coordination mode to construct target frameworks. As an illustration of this strategy, a series of In-MOFs based on the H(2)FcDCA ligand have been successfully synthesized. The introduction of rigid OX2- ligands and large cation template leads to the syntheses of various In-MOFs. Furthermore, introducing functional cations and a ferrocene unit endows them with good third order nonlinear optical properties and redox activity.
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