Hydrothermal Synthesis of Well-Defined Red-Emitting Eu-Doped GdPO4 Nanophosphors and Investigation of Their Morphology and Optical Properties

Rare-earth-doped GdPO4 nanoparticles have recently attracted much scientific interest due to the simultaneous optical and magnetic properties of these materials and their possible application in bio-imaging. Herein, we report the hydrothermal synthesis of GdPO4:Eu3+ nanoparticles by varying different synthesis parameters: pH, : molar ratio, and Eu3+ concentration. It turned out that the Eu3+ content in the synthesized nanoparticles had little effect on particle shape and morphology. The synthesis media pH, however, has showed a pronounced impact on particle size and distribution, i.e., the nanoparticle length can be adjusted from hundreds to tens of nanometers by changing the pH from 2 to 11, respectively. Increasing the : molar ratio resulted in a decrease in nanoparticle length and an increase in its width. The temperature-dependent measurements in the 77-500 K range revealed that the GdPO4:50%Eu3+ sample maintains half of its emission intensity, even at room temperature (TQ(1/2) = 291 +/- 19 K).

Automated summary

Rare-earth-doped GdPO4 nanoparticles with simultaneous optical and magnetic properties have gained much attention for their potential application in bio-imaging. In this study, GdPO4:Eu3+ nanoparticles were synthesized hydrothermally by adjusting synthesis parameters such as pH, :molar ratio, and Eu3+ concentration. The results showed that the Eu3+ content had little effect on particle shape and morphology, while the pH had a pronounced impact on particle size and distribution. Increasing the :molar ratio resulted in a decrease in nanoparticle length and an increase in width. The synthesized GdPO4:50%Eu3+ sample exhibited significant emission intensity even at room temperature.