Journal
CRYSTALS
Volume 13, Issue 1, Pages -Publisher
MDPI
DOI: 10.3390/cryst13010059
Keywords
phosphonium; self-assembly; crystal structure; Hirshfeld surface; biphenyl
Ask authors/readers for more resources
This study examines the single crystal structures of two bulky phosphonium compounds and investigates their self-assembly behavior. It is found that the organic cations form stable stacked columns with voids occupied by anions or solvent molecules. The analysis suggests that hydrogen bonding plays a dominant role in stabilizing the self-assembly.
Quaternary phosphonium salts are popular candidates used in many chemical transformations and synthetic chemistry, notably in catalysis. We have examined the single crystals of two bulky phosphonium compounds, tetra([1,1 '-biphenyl]-4-yl) phosphonium dicyanamide (C48H36P+center dot N(CN)(2)(-), compound 1), and tetra([1,1 '-biphenyl]-4-yl) phosphonium bromide hydrate (C48H36P+center dot Br-, CH3CN, H2O, compound 2), and herein report the structural properties for the compounds with an emphasis on the influence of the ion-ion interaction towards self-assembly; the overall self-assembly for both structures is very similar, with subtle differences in the cell parameters. The symmetrical tetra ([1,1 '-biphenyl]-4-yl) phosphonium cations in both compounds self-assembled to form robust stacked columns in the solid-state, with voids occupied by anions or solvent molecules. Quantitative examination of intermolecular interactions using Hirshfeld surface analysis found that classical and non-classical hydrogen bonding appears to be the dominant contributor in stabilizing the self-assembly in both cases. The present work can not only benefit in understanding the mutual interaction between the sterically encumbered tetra ([1,1 '-biphenyl]-4-yl) phosphonium cations and between counterions, but also provide insights for the self-assembled arrays in the solid-state.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available