Influence of Urea Content in Deep Eutectic Solvents on Thermoplastic Starch Films' Properties

Featured Application Thermoplastic starch (TPS) materials with urea-rich eutectic mixtures are obtained from cheap, available and abundant sources. They can be used as ecofriendly agricultural plastics because urea-based DESs act not only as starch plasticizers, but they also constitute sources of fertilizer, which can be released from the materials. The goal of the study was to prepare deep eutectic solvents (DESs) with different urea (U) contents and apply them as potato-starch plasticizers to investigate the influence of various DES compositions on the physicochemical properties of thermoplastic starch (TPS) obtained via thermocompression. As hydrogen bond acceptors, quaternary ammonium compounds, choline chloride (CC) and betaine (B-anhydrous and monohydrate) were used. The molar ratios of CC or B to U were 1:2, 1:3, 1:4 and 1:5. Before starch processing, the DESs were thermally characterized (DSC, TGA). The increase in U content in the eutectics led to higher phase-transition temperatures and lower thermal stability. The influence of the DESs on thermocompressed TPS mechanical (tensile test) and thermal-mechanical (DMTA) properties, morphology (XRD and FTIR), sorption/dissolution behavior and surface contact angle was investigated. The mechanical tests revealed that the increase in U led to higher elongation at break and a highly amorphous structure. The FTIR results indicated that the starch underwent some carbamation derivatization with the presence of B. The DESs with high U content plasticized starch effectively; therefore, preliminary extrusion tests for starch were performed with selected CC and B-based DES with the molar ratio of 1:5.

Automated summary

In this study, deep eutectic solvents (DESs) with different urea (U) contents were prepared and used as plasticizers for potato-starch. The influence of different DES compositions on the physicochemical properties of thermoplastic starch (TPS) was investigated. The results showed that increasing the U content led to higher phase-transition temperatures and lower thermal stability. Additionally, higher U content resulted in higher elongation at break and a highly amorphous structure in the TPS.