Journal
JOURNAL OF POWER SOURCES
Volume 323, Issue -, Pages 97-106Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jpowsour.2016.05.033
Keywords
Flow battery; Energy storage; Lithium-ion battery; Carbon-free; Lithium titanium oxide; Suspension
Funding
- National Science Foundation [ECCS-1405134]
- Applied Battery Research (ABR) for Transportation Program
- Directorate For Engineering
- Div Of Electrical, Commun & Cyber Sys [1405134] Funding Source: National Science Foundation
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A new type of non-aqueous redox couple without carbon additives for flow batteries is proposed and the target anolyte chemistry is demonstrated. The so-called Solid Dispersion Redox Couple incorporates solid electroactive materials dispersed in organic lithium-ion battery electrolyte as its flowing suspension. In this work, a unique and systematic characterization approach has been used to study the flow battery redox couple in half cell demonstrations relative to a lithium electrode. An electrolyte laden with Li4Ti5O12 (LTO) has been characterized in multiple specially designed lithium half cell configurations. The flow battery redox couple described in this report has relatively low viscosity, especially in comparison to other flow batteries with solid active materials. The lack of carbon additive allows characterization of the electrochemical properties of the electroactive material in flow without the complication of conductive additives and unambiguous observation of the electrorheological coupling in these dispersed particle systems. (C) 2016 Elsevier B.V. All rights reserved.
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