Visible-Light-Active N-Doped TiO2 Photocatalysts: Synthesis from TiOSO4, Characterization, and Enhancement of Stability Via Surface Modification

This paper describes the chemical engineering aspects for the preparation of highly active and stable nanocomposite photocatalysts based on N-doped TiO2. The synthesis is performed using titanium oxysulfate as a low-cost inorganic precursor and ammonia as a precipitating agent, as well as a source of nitrogen. Mixing the reagents under a control of pH leads to an amorphous titanium oxide hydrate, which can be further successfully converted to nanocrystalline anatase TiO2 through calcination in air at an increased temperature. The as-prepared N-doped TiO2 provides the complete oxidation of volatile organic compounds both under UV and visible light, and the action spectrum of N-doped TiO2 correlates to its absorption spectrum. The key role of paramagnetic nitrogen species in the absorption of visible light and in the visible-light-activity of N-doped TiO2 is shown using the EPR technique. Surface modification of N-doped TiO2 with copper species prevents its intense deactivation under highly powerful radiation and results in a nanocomposite photocatalyst with enhanced activity and stability. The photocatalysts prepared under different conditions are discussed regarding the effects of their characteristics on photocatalytic activity under UV and visible light.

Automated summary

This paper describes the chemical engineering aspects of the preparation of highly active and stable nanocomposite photocatalysts based on N-doped TiO2. The synthesis involves the use of titanium oxysulfate as a precursor and ammonia as a precipitant and nitrogen source. The as-prepared N-doped TiO2 exhibits significant oxidation activity for volatile organic compounds under both UV and visible light due to its absorption spectrum. Surface modification with copper species enhances the activity and stability of the photocatalyst. The effects of different preparation conditions on the photocatalytic activity under UV and visible light are discussed.