Journal
JOURNAL OF POWER SOURCES
Volume 309, Issue -, Pages 135-140Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jpowsour.2016.01.092
Keywords
Bismuth sulfide; Nanorods; Anode; Sodium-ion batteries
Funding
- Automotive CRC [1-111]
- National Natural Science Foundation of China [21373184]
- Public Projects of Zhejiang Province [2015C31039]
- Anhui Provincial Natural Science Foundation [1608085QB35]
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Exploring high-performance anode materials is currently one of the most urgent issues towards practical sodium-ion batteries (SIBs). In this work, Bi2S3 is demonstrated to be a high-capacity anode for SIBs for the first time. The specific capacity of Bi2S3 nanorods achieves up to 658 and 264 mAh g(-1) at a current density of 100 and 2000 mA g(-1), respectively. A full cell with Na3V2(PO4)(3)-based cathode is also assembled as a proof of concept and delivers 340 mAh g(-1) at 100 mA g(-1). The sodium storage mechanism of Bi2S3 is investigated by ex-situ XRD coupled with high-resolution TEM (HRTEM), and it is found that sodium storage is achieved by a combined conversion-intercalation mechanism. (C) 2016 Elsevier B.V. All rights reserved.
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