Journal
JOURNAL OF POWER SOURCES
Volume 316, Issue -, Pages 53-59Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jpowsour.2016.03.075
Keywords
Copper sulfide; Counter electrode; Electrodeposition; Electrocatalytic activity; Quantum dot-sensitized solar cell
Funding
- Basic Science Research Program through the National Research Foundation of Korea - Ministry of Education [NRF- 2015R1D1A3A01016158]
- Human Resources Program in Energy Technology of the Korea Institute of Energy Technology Evaluation and Planning from the Ministry of Trade, Industry & Energy, Republic of Korea [20154030200760]
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Copper sulfide (Cu2S) films were deposited on F-doped SnO2 (FTO) substrates via the electrodeposition (ED) of copper (Cu) nanoparticles followed by sulfurization. The Cu nanoparticles were deposited on FTO substrates for various ED times ranging from 10 to 30 min at a constant-0.4 V. The FTO/Cu films consisted of flower-like nanoparticles comprised of randomly-clustering nanoflakes. The Cu nano particles electrodeposited for 10 min (FTO/Cu (10 min)) were dispersed sparsely over the FTO substrate, whereas the FTO/Cu (20 and 30 min) provided increased coverage. Unlike FTO/Cu2S (10 min), the FTO/Cu2S (20 and 30 min) consisted of vertically-standing large Cu2S nanosheets with numerous small nanosheets in between. This was attributed to the sufficient number of Cu seed nanoflakes, which not only facilitate ion transport of the redox couple but also increased the surface area, leading to significantly enhanced electrocatalytic activity. The quantum dot-sensitized solar cell (QD-SSC) with FTO/Cu2S (20 min) exhibited a significantly improved cell efficiency of 4.58%, compared to those with Pt and FTO/Cu2S (10 min). The QD-SSC with the FTO/Cu2S (30 min) showed similar cell efficiency to that with the FTO/Cu2S (20 min), despite the larger surface area because of its amorphous crystallographic structure offsetting the electrocatalytic activity. (C) 2016 Elsevier B.V. All rights reserved.
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