Journal
JOURNAL OF POWER SOURCES
Volume 315, Issue -, Pages 9-15Publisher
ELSEVIER
DOI: 10.1016/j.jpowsour.2016.03.025
Keywords
Reduced graphene oxide; Porous silicon; Rice husks; High-rate; Anode
Funding
- NSFC [21205112, 21225524, 21375124, 21475122, 21127006]
- Department of Science and Techniques of Jilin Province [20120308, 201215091, SYHZ0006]
- Chinese Academy of Sciences [YZ201354, YZ201355]
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We report a new method for synthesizing reduced graphene oxide (rGO)-porous silicon composite for lithium-ion battery anodes. Rice husks were used as a as a raw material source for the synthesis of porous Si through magnesiothermic reduction process. The as-obtained composite exhibits good rate and cycling performance taking advantage of the porous structure of silicon inheriting from rice husks and the outstanding characteristic of graphene. A considerably high delithiation capacity of 907 mA h g(-1) can be retained even at a rate of 16 A g(-1). A discharge capacity of 830 mA h g(-1) at a current density of 1 A g(-1) was delivered after 200 cycles. This may contribute to the further advancement of Si-based composite anode design. (C) 2016 Elsevier B.V. All rights reserved.
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