4.5 Article

Anion Exchange Membrane Water Electrolysis Based on Nickel Ferrite Catalysts

Journal

CHEMELECTROCHEM
Volume 10, Issue 1, Pages -

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/celc.202201056

Keywords

nickel ferrite catalysts; anionic exchange membrane; electrolyser; oxygen evolution reaction; hydrogen production

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A nickel ferrite catalyst was prepared and successfully deposited on an anion exchange membrane. The catalyst demonstrated higher current density than commercial catalysts and showed good stability during a 120-hour test.
A nickel ferrite was prepared by a liquid-phase method and used as an oxygen evolution catalyst in an anion exchange membrane electrolyser. A complete physicochemical characterization of the catalyst was performed through X-ray diffraction (XRD), Transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS). Then, the nickel ferrite was deposited by spray coating technique onto a Fumasep (R) FAA3-50 anion-exchange membrane to realize a catalyst-coated membrane (CCM), and tested in a 5 cm(2) single cell setup in the so-called zero-gap configuration. At 60 degrees C and 2.2 V, a current density of 3 A/cm(2) was reached, which is higher than that obtained with NiO and IrO2 commercial catalysts. Moreover, a chronoamperometric test of 120 h highlighted the good stability of the synthesized catalyst.

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