Journal
CATALYSTS
Volume 13, Issue 1, Pages -Publisher
MDPI
DOI: 10.3390/catal13010012
Keywords
C-H; C-H coupling; dibenzofuran; carbazole; dibenzothiophene; palladium
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Dibenzo-fused five-membered heteroaromatic compounds, such as dibenzofuran, carbazole, and dibenzothiophene, are important structural units in various polycyclic heteroaromatic compounds. The intramolecular C-H/C-H biaryl coupling of diaryl (thio)ethers and amines based on palladium(II) catalysis under oxidative conditions is an effective method for their construction. This mini-review briefly summarizes representative examples of constructing structurally intriguing pi-extended polycyclic heteroaromatics through catalytic coupling reactions.
Dibenzo-fused five-membered heteroaromatic compounds, including dibenzofuran, carbazole, and dibenzothiophene, are fundamental structural units in various important polycyclic heteroaromatic compounds. The intramolecular C-H/C-H biaryl coupling of diaryl (thio)ethers and amines based on palladium(II) catalysis under oxidative conditions is known to be one of the most effective, step-economic methods for their construction. Representative examples for the construction of structurally intriguing pi-extended polycyclic heteroaromatics through catalytic coupling reactions are briefly summarized in this mini-review.
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