4.5 Article

Preparation of activated carbons from poplar wood by chemical activation with KOH

Journal

JOURNAL OF POROUS MATERIALS
Volume 24, Issue 1, Pages 193-202

Publisher

SPRINGER
DOI: 10.1007/s10934-016-0252-6

Keywords

Activated carbon; Poplar wood; KOH; Chemical activation; Microporosity; Thermogravimetric analysis

Funding

  1. International Joint Research and Development Project of Tianjin Talent Introduction and Science and Technology Cooperation Plan [14RCGFGX00850]

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Low-cost activated carbons were prepared from poplar wood by chemical activation with KOH as a chemical activating agent. The thermal behavior of KOH-impregnated poplar wood was analyzed in detail via the Thermogravimetric analysis (TG, DTG and DSC). Moreover, the effects of impregnation ratio, activation temperature and activation time on the porous structure were investigated. Results showed that KOH has catalytic effect which could promote the pyrolysis of poplar wood at lower activation temperature. The activated carbons from poplar wood with KOH activation could be formed at 550-700 degrees C. The specific surface area and pore volume of activated carbon increased with increasing the impregnation ratio, activation temperature and activation time. Moreover, influence of increasing impregnation ratio on the porosity of activated carbon is sensitive to activation time. The maximum specific surface area (1551 m(2)/g) activated carbon with uniform micropores distribution was obtained at activation temperature of 700 degrees C, impregnation ratio of 3/1 and activation time of 30 min. Carbon skeleton could break seriously when activation temperature is higher than 750 degrees C.

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