Journal
JOURNAL OF MATERIALS CHEMISTRY C
Volume 11, Issue 5, Pages 1772-1781Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2tc04252e
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This work reports the molecular beam epitaxy (MBE) of two-dimensional (2D) GaSe1-xTex ternary alloys, which have attracted a lot of interest in physics for prospective electronics and optoelectronics. The majority of hexagonal-GaSe1-xTex phase can be guaranteed on a GaN/sapphire platform without a visible sign of phase transition under specific growth conditions. The photoresponse performance of the hexagonal ternary alloy has greatly enhanced compared to the h-GaSe binary.
This work reports molecular beam epitaxy (MBE) of two-dimensional (2D) GaSe1-xTex ternary alloys that have recently attracted a lot of interest in physics for prospective electronics and optoelectronics even though they face crucial challenges in their epitaxial technology. Disregarding a distinction in crystal phase symmetry of two end-terminals, i.e., hexagonal-GaSe (h-GaSe) and monoclinic-GaTe (m-GaTe), the majority of hexagonal-GaSe1-xTex (h-GaSe1-xTex) phase on a GaN/sapphire platform is guaranteed under our specific growth conditions without a visible sign of phase transition. We have also proposed extracting the Te composition of the ternary alloy via the experimental in-plane lattice constant, which is consistent with those indicated from energy dispersion X-ray data. Fascinatingly, the experimental and predictable band emission versus Te content displays a continuous redshift from 1.78 eV (h-GaSe) to 1.25 eV (h-GaSe0.4Te0.6) then a reversible blueshift to 1.46 eV (h-GaTe). Importantly, benefiting from the presence of Te incorporated atoms, the photoresponse performance of the hexagonal ternary alloy has greatly enhanced in comparison to the h-GaSe binary in terms of photocurrent density (up to 1250 nA cm(-2) for h-GaSe0.65Te0.35 at only 300 mV bias). Overall, the results pave a way for phase/physical engineering of the alloys through the MBE process and realizing self-powered wafer-scale photodetectors based on 2D Ga-based monochalcogenide epitaxial thin films.
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