4.8 Article

Design Principles for Heteroatom-Doped Carbon Nanomaterials as Highly Efficient Catalysts for Fuel Cells and Metal-Air Batteries

Journal

ADVANCED MATERIALS
Volume 27, Issue 43, Pages 6834-+

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201503211

Keywords

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Funding

  1. Air Forces MURI [FA9550-12-1-0037]
  2. National Science Foundation [NSF-AIR-IIP-1343270, NSF-CMMI-1363123]
  3. Directorate For Engineering
  4. Div Of Civil, Mechanical, & Manufact Inn [1363123] Funding Source: National Science Foundation
  5. Directorate For Engineering
  6. Div Of Industrial Innovation & Partnersh [1343270] Funding Source: National Science Foundation
  7. Div Of Civil, Mechanical, & Manufact Inn
  8. Directorate For Engineering [1400274] Funding Source: National Science Foundation

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Oxygen reduction reaction/oxygen evolution reaction (ORR/OER) catalytic activities of p-orbital heteroatom-doped carbon nanomaterials are demonstrated to correlate to the combination of the electron affinity and electronegativity of doping elements, which serves as an activity descriptor for the entire family of p-block element dopants. Such a descriptor has predictive power and enables effective design of new bifunctional catalysts with enhanced ORR/OER activities.

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