4.6 Article

Super Broadband Near-Infrared Solid Solution Phosphors with Adjustable Peak Wavelengths from 1165 to 875 nm for NIR Spectroscopy Applications

Journal

ADVANCED OPTICAL MATERIALS
Volume 11, Issue 5, Pages -

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adom.202202291

Keywords

long-wavelength NIR emission; solid solution strategy; spectroscopy detection; super broad-band luminescence; d-d transition of Cr3+

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This study investigates tunable near-infrared luminescence of a Cr3+-activated LiInGeO4 phosphor and achieves emission control and broadening through the design of different host structures. The near-infrared emission generated by Cr3+ is confirmed and characterized using various experimental methods, and the luminescence mechanism is discussed. The results demonstrate the potential application of the synthesized phosphor in near-infrared spectroscopy detection.
Cr3+-activated near-infrared (NIR) phosphors have attracted wide attention owing to applications in phosphor-converted light-emitting diodes (pc-LED) for spectroscopy. Because a broader spectrum covers more information to detect, the width of the spectrum is an important parameter to consider. Here, the blue LED excitable ultra-broadband Cr3+-activated LiInGeO4 phosphors, which exhibit unprecedented long-wavelength NIR emission with a wide full-width at half maximum (FWHM) of 305 nm, are developed. The overall emission tuning from 1165 to 875 nm with broadened FWHM from 305 to 508 nm is realized through designing continuous solid solution hosts of LiIn1-zSczGeO4/(LiIn)(1-)yMg2yGeO4 and finite solid solution hosts of (LiIn)(1-)yZn2yGeO4:Cr3+. The observation of such long-wavelength NIR from Cr3+ not Cr4+ is studied and confirmed by electron paramagnetic resonance, X-ray absorption near-edge structure, and steady-/transient-state photoluminescence. The formation of finite solid solutions induces the change in the local structure of Cr3+ that ultimately leads to the observation of super broadband (FWHM = 508 nm) luminescence. The luminescence mechanism is discussed in this study. Finally, this study demonstrates that the as-synthesized phosphors with tunable NIR luminescence can be well used in NIR pc-LEDs for spectroscopy detection.

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