Groundwater Vulnerability and Potentially Toxic Elements Associated with the Iron Mining District of Ouixane (Northeast of Morocco)

This study aims to investigate the groundwater vulnerability concerning potentially toxic elements in the vicinity of the abandoned iron mine of Ouixane (Morocco). A modified DRASTIC method (DRSTI) is proposed with satisfactory results. High vulnerability zones represent 40% of the study area, while medium and low vulnerability represent, respectively, 42% and 18% of the study area. These results have been validated by groundwater geochemical analyses of potentially toxic elements carried out in the framework of previous studies in the same area. Thus, the superposition of the waste rock and tailings map with the vulnerability map showed that the latter is located in areas of high to medium vulnerability and therefore constitutes the main cause of the deterioration of the geochemical quality of groundwater. Otherwise, the vulnerability method showed that the main parameters that significantly affect the vulnerability are: the depth of water (D), net recharge (R), and the unsaturated zone (I), while the other parameters do not significantly affect the model used and do not have much influence on the results of the vulnerability assessment. The method used allowed us to locate the most vulnerable areas to potentially metallic toxic elements pollution resulting from the abandoned iron mine of Ouixane, and it constitutes a tool for decision support and for developing effective action plans to mitigate and monitor the effects of the transfer of potentially toxic elements pollution to groundwater.

Automated summary

This study aims to investigate the vulnerability of groundwater to potentially toxic elements near the abandoned iron mine of Ouixane in Morocco. A modified DRASTIC method (DRSTI) was used and showed satisfactory results. The study found that high vulnerability zones accounted for 40% of the area, while medium and low vulnerability zones accounted for 42% and 18% respectively. The results were validated using groundwater geochemical analyses of potentially toxic elements, which confirmed that the geochemical quality of groundwater was mainly affected by the waste rock and tailings from the mine.