Journal
POLYMERS
Volume 15, Issue 3, Pages -Publisher
MDPI
DOI: 10.3390/polym15030704
Keywords
biodegradation; aging; water immersion; salt fog; natural fiber; polymer composites
Categories
Ask authors/readers for more resources
Biological agents, specifically fungal colonization, cause significant damage to oil palm empty fruit bunch (OPEFB) fiber-reinforced acrylic thermoplastic composites. The colonization is observed after continuous salt fog treatment, mainly by different species of Aspergillus spp. genus. The salt fog also promotes the growth of filamentous fungi, leading to the degradation of OPEFB fiber cell walls. As a result, the composites become fragile, with increased Young's modulus and decreased elongation at break and toughness.
Biological agents and their metabolic activity produce significant changes over the microstructure and properties of composites reinforced with natural fibers. In the present investigation, oil palm empty fruit bunch (OPEFB) fiber-reinforced acrylic thermoplastic composites were elaborated at three processing temperatures and subjected to water immersion, Prohesion cycle, and continuous salt-fog aging testing. After exposition, microbiological identification was accomplished in terms of fungal colonization. The characterization was complemented by weight loss, mechanical, infrared, and thermogravimetric analysis, as well as scanning electron microscopy. As a result of aging, fungal colonization was observed exclusively after continuous salt fog treatment, particularly by different species of Aspergillus spp. genus. Furthermore, salt spray promoted filamentous fungi growth producing hydrolyzing enzymes capable of degrading the cell walls of OPEFB fibers. In parallel, these fibers swelled due to humidity, which accelerated fungal growth, increased stress, and caused micro-cracks on the surface of composites. This produced the fragility of the composites, increasing Young's modulus, and decreasing both elongation at break and toughness. The infrared spectra showed changes in the intensity and appearance of bands associated with functional groups. Thermogravimetric results confirmed fungal action as the main cause of the deterioration.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available