4.7 Article

Post-Treatment of Tannic Acid for Thermally Stable PEDOT:PSS Film

Journal

POLYMERS
Volume 14, Issue 22, Pages -

Publisher

MDPI
DOI: 10.3390/polym14224908

Keywords

PEDOT; PSS; tannic acid; thermal stability; surface-treatment; electrical conductivity

Funding

  1. University of Suwon
  2. Advanced Materials Analysis Center, The University of Suwon

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As a conductive polymer in the field of organic electronics, poly(3,4-ethylenedioxythiophene) doped with poly(styrene sulfonate) (PEDOT:PSS) can be operated at low temperatures but is susceptible to damage under high temperature conditions. Surface treatment of PEDOT:PSS with tannic acid increases its thermal stability, allowing it to maintain good conductivity and film properties at high temperatures.
As a poly (3,4-ethylenedioxythiophene) doped with poly (styrene sulfonate), PEDOT:PSS is well known for its conductive polymer in a field of organic electronics. PEDOT:PSS can be widely operated as electronics under low temperature conditions; however, the layer can be easily damaged by high temperature conditions, while in fabrication or in the operation of electronics. Therefore, enhancing the thermal stability of PEDOT:PSS can be a novel strategy for both fabrication and operating varieties. Herein, PEDOT:PSS is the surface-treated with tannic acid to increase the thermal stability. A large number of phenols in tannic acid not only provide UV absorption ability, but also thermal stability. Therefore, tannic-treated PEDOT:PSS film sustained 150 degrees C for 96 h because of its initial conductivity. Moreover, surface properties and its bonding nature was further examined to show that the tannic acid does not damage the electrical and film properties. The method can be widely used in the field of organic electronics, especially because of its high stability and the high performance of the devices.

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