Journal
RSC ADVANCES
Volume 13, Issue 3, Pages 1935-1942Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2ra07853h
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Pyrolysis of low-rank coal in CO2 atmosphere can reduce carbon emissions while comprehensively utilizing coal resources. The influences of CO2 on the pyrolysis characteristic and product distribution of low-rank coal are analyzed. It is found that CO2 inhibits the conversion of char to tar in the early stage, but promotes the decomposition of char and increases the yield of tar and pyrolysis gas in the later stage. Reforming reaction of CO2 with alkanes generates free hydrogen radicals, which promotes the cleavage of various bonds and increases the yield of light tar.
Pyrolysis of low-rank coal in CO2 atmosphere can reduce carbon emissions while comprehensively utilizing coal resources. Based on ReaxFF molecular dynamics (ReaxFF-MD), the pyrolysis processes of low-rank coal in inert and CO2 atmosphere are simulated. By comparing the evolution of pyrolysis products, the influences of CO2 on the pyrolysis characteristic and product distribution are analyzed. It is found that CO2 slightly inhibits the conversion of char to tar in the early stage of pyrolysis. In the later stage, CO2 significantly promotes the decomposition of char and increases the yield of tar and pyrolysis gas. According to the different bond breaking behaviors of coal molecules, the pyrolysis process can be divided into pyrolysis activation stage, initial pyrolysis stage, accelerated pyrolysis stage and secondary pyrolysis stage. The reforming reaction of CO2 with alkanes generates free hydrogen radicals, which promotes the cleavage of ether bond, C-ar-C-ar bridge bond and aliphatic C-C bond. Compared with in inert atmosphere, final yield of light tar in CO2 atmosphere increases from 17.98% to 20.68%. In general, the CO2 atmosphere helps to improve the tar yield and tar quality of low-rank coal pyrolysis.
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