Journal
RSC ADVANCES
Volume 13, Issue 4, Pages 2451-2457Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2ra07826k
Keywords
-
Categories
Ask authors/readers for more resources
The Lewis acidity of organoboronates [B(pin), B(neop), B(cat), B(eg), B(nad)] and organoboronamides [B(dan), B(aam), B(mdan)] can be uniformly evaluated by computed ammonia affinity (AA), but other methods (LUMO energies, global electrophilicity index (GEI), fluoride ion affinity (FIA)) are only partially applicable. The relationships between the AA values and structural characters including the B-X bond lengths, the X-B-X angles, and the changes in the B-X bond lengths in the formation of the ammonia adducts were also described.
Lewis acidity of organoboronates [B(pin), B(neop), B(cat), B(eg), B(nad)] and organoboronamides [B(dan), B(aam), B(mdan)] has been found to be unifiedly evaluated by computed ammonia affinity (AA), while other methods [LUMO energies, global electrophilicity index (GEI), fluoride ion affinity (FIA)] were only partially applicable. The relationships between the AA values and such structural characters including the B-X bond lengths, the X-B-X angles, and the changes in the B-X bond lengths in the formation of the ammonia adducts were also described.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available