Electrochemical, Biological, and Technological Properties of Anodized Titanium for Color Coded Implants

Anodization coloring of titanium tools or implants is one of the common methods for the differentiation of each application by its size or type. Commercial purity titanium grade 4 plates (50 x 20 x 0.1 mm) were tested to obtain their electrochemical and other technological properties. The coloring process was done using the potential of 15, 30, 45, 60, and 75 Volts for 5 s in 1 wt. % citric acid in demineralized water solution. Organic acids solutions generally produce better surface quality compared to inorganic acids. The contact angle of colored surfaces was measured by the sessile drop method. Electrochemical impedance spectroscopy and potentiodynamic polarization were used for the determination of selected electrochemical and corrosion parameters of the tested surfaces. It was found that the anodization process decreases corrosion potential significantly. It was also confirmed that a higher potential used for anodization results in higher polarization resistance but also a decrease in corrosion potential. The anodization process at 75 V produces surfaces with the lowest corrosion rate under 1 nm/year and the noblest corrosion potential. It was confirmed that the anodization process in citric acid does not affect titanium cytotoxicity.

Automated summary

Anodization coloring is commonly used for differentiation of titanium tools or implants. Commercial purity titanium grade 4 plates were tested for their properties. The coloring process was done using different potentials in citric acid solution. The anodization process significantly decreases corrosion potential and higher potential results in higher polarization resistance but lower corrosion potential. The anodization process at 75 V produces surfaces with the lowest corrosion rate and noblest corrosion potential, without affecting titanium cytotoxicity.