Effect of h-BN Support on Photoluminescence of ZnO Nanoparticles: Experimental and Theoretical Insight

Herein we report a simple and easily scalable method for fabricating ZnO/h-BN composites with tunable photoluminescence (PL) characteristics. The h-BN support significantly enhances the ultraviolet (UV) emission of ZnO nanoparticles (NPs), which is explained by the ZnO/h-BN interaction and the change in the electronic structure of the ZnO surface. When h-BN NPs are replaced with h-BN microparticles, the PL in the UV region increases, which is accompanied by a decrease in visible light emission. The dependence of the PL properties of ZnO NPs on the thickness of h-BN carriers, observed for the first time, is explained by a change in the dielectric constant of the support. A quantum chemical analysis of the influence of the h-BN thickness on the electron density redistribution at the wZnO/h-BN interface and on the optical properties of the wZnO/h-BN composites was carried out. Density functional theory (DFT) calculations show the appearance of hybridization at the h-BN/wZnO interface and an increase in the intensity of absorption peaks with an increase in the number of h-BN layers. The obtained results open new possibilities for controlling the properties of ZnO/h-BN heterostructures for various optical applications.

Automated summary

A method for fabricating ZnO/h-BN composites with tunable photoluminescence characteristics is reported. The h-BN support enhances the UV emission of ZnO nanoparticles and changes the electronic structure of the ZnO surface. Replacing h-BN nanoparticles with h-BN microparticles increases the UV photoluminescence and decreases the visible light emission. The dependence of the photoluminescence properties on the thickness of h-BN carriers is explained by the change in the dielectric constant. Density functional theory calculations show hybridization at the h-BN/wZnO interface and an increase in absorption peak intensity with an increase in the number of h-BN layers. These results open new possibilities for controlling the properties of ZnO/h-BN heterostructures for optical applications.