Journal
MATERIALS
Volume 15, Issue 21, Pages -Publisher
MDPI
DOI: 10.3390/ma15217801
Keywords
charge-transfer; molecular electronics; transannular pi-pi interaction; [2,2]paracyclophane-1,9-dienes (PCD)
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Funding
- Funding of Southern Marine Science and Engineering Guangdong Laboratory [012S22004-006]
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This paper investigates the influence of transannular pi-pi interaction on the carrier transport in molecular wires using the STM break junction technique. It is found that the carrier transport features of these molecular wires can be systematically controlled through the transannular pi-pi interaction.
This paper describes the influence of the transannular pi-pi interaction in controlling the carrier transport in molecular wires by employing the STM break junction technique. Five pentaphenylene-based molecular wires that contained [2.2]paracyclophane-1,9-dienes (PCD) as the building block were prepared as model compounds. Functional substituents with different electronic properties, ranging from strong acceptors to strong donors, were attached to the top parallel aromatic ring and used as a gate. It was found that the carrier transport features of these molecular wires, such as single-molecule conductance and a charge-tunneling barrier, can be systematically controlled through the transannular pi-pi interaction.
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