Journal
MATERIALS
Volume 16, Issue 1, Pages -Publisher
MDPI
DOI: 10.3390/ma16010370
Keywords
skutterudites; CoSb3; thermal expansion; rattling effect; thermoelectrics
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In this study, Gd-filled skutterudite GdxCo4Sb12 was prepared under high pressure and moderate temperature. The structural characterization revealed a filling fraction of x = 0.033(2) and an average bond length of 3.3499(3) angstrom. The lattice thermal expansion and Debye temperature were determined, showing that the application of the harmonic Debye theory underestimates the Debye temperature in skutterudites. The presence of Gd atom contributed to an ultra-low thermal conductivity and high thermoelectric efficiency.
In this work, Gd-filled skutterudite GdxCo4Sb12 was prepared using one step method under high pressure in a piston-cylinder-based press at 3.5 GPa and moderate temperature of 800 degrees C. A detailed structural characterization was performed using synchrotron X-ray diffraction (SXRD), revealing a filling fraction of x = 0.033(2) and an average bond length of 3.3499(3) angstrom. The lattice thermal expansion accessed via temperature-dependent SXRD led to a precise determination of a Debye temperature of 322(3) K, from the fitting of the unit-cell volume expansion using the second order Gruneisen approximation. This parameter, when evaluated through the mean square displacements of Co and Sb, displayed a value of 265(2) K, meaning that the application of the harmonic Debye theory underestimates the Debye temperature in skutterudites. Regarding the Gd atom, its intrinsic disorder value was similar to 5x and similar to 25x higher than those of the Co and Sb, respectively, denoting that Gd has a strong rattling behavior with an Einstein temperature of theta(E) = 67(2) K. As a result, an ultra-low thermal conductivity of 0.89 W/m center dot K at 773 K was obtained, leading to a thermoelectric efficiency zT of 0.5 at 673 K.
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