4.8 Article

Direct-Ink-Write 3D Printing of Programmable Micro-Supercapacitors from MXene-Regulating Conducting Polymer Inks

Related references

Note: Only part of the references are listed.
Article Chemistry, Multidisciplinary

3D Printed Template-Assisted Assembly of Additive-Free Ti3C2Tx MXene Microlattices with Customized Structures toward High Areal Capacitance

Chuang Yang et al.

Summary: A 3D printed template-assisted method is used to fabricate additive-free 3D architected MXene aerogels with controllable structures and high performance. The MXene ink with a wide range of concentrations allows for the production of MXene aerogels with high structural freedom and fine feature size.

ACS NANO (2022)

Article Chemistry, Multidisciplinary

Inkjet Printed Disposable High-Rate On-Paper Microsupercapacitors

Zheng Li et al.

Summary: This research developed microsupercapacitors using a novel conductive ink that can be inkjet-printed on commercial paper substrates, exhibiting high efficiency and environmental performance, as well as excellent performance in cycle life, flexibility, and rate capability. These metal-free devices show lower eco-toxicity and global warming potential in comparison to other on-paper microsupercapacitors.

ADVANCED FUNCTIONAL MATERIALS (2022)

Article Chemistry, Multidisciplinary

3D Printed Ti3C2Tx MXene/Cellulose Nanofiber Architectures for Solid-State Supercapacitors: Ink Rheology, 3D Printability, and Electrochemical Performance

Guoqiang Zhou et al.

Summary: This study improved the rheological properties of MXene-based inks by utilizing cellulose nanofibers (CNFs), successfully printing 3D architectures with superior shape fidelity and geometric accuracy, leading to enhanced capacitive performance.

ADVANCED FUNCTIONAL MATERIALS (2022)

Article Chemistry, Multidisciplinary

Additive Manufacturing of Ti3C2-MXene-Functionalized Conductive Polymer Hydrogels for Electromagnetic-Interference Shielding

Ji Liu et al.

Summary: This study develops a hydrogel ink and proposes a freeze-thawing protocol to achieve 3D printing of conductive polymer hydrogels with high conductivity and shape fidelity. The printed hydrogel exhibits high conductivity, good mechanical properties, and customizable applications.

ADVANCED MATERIALS (2022)

Article Engineering, Environmental

Continuous PEDOT:PSS nanomesh film: Towards aqueous AC line filtering capacitor with ultrahigh energy density

Zhou Li et al.

Summary: Filtering capacitors with high energy densities play a critical role in stabilizing pulse signals in circuits. This work presents an ultrafast aqueous electrochemical capacitor based on polymer networks, showing outstanding performance in ripple filtering and signal smoothing across a wide frequency range.

CHEMICAL ENGINEERING JOURNAL (2022)

Article Materials Science, Multidisciplinary

High-stability conducting polymer-based conformal electrodes for bio-/iono-electronics

Bowen Yao et al.

Summary: Compared to conventional rigid electronics, polymer-based soft electronics that conform to irregular shapes of organisms have advantages in long-term bio-interface interactions. However, the current polymer materials are unstable in alkaline environments, reductants, and applied voltage, leading to performance deterioration. This study proposes a coating strategy using reduced-graphene-oxide thin layers to enhance stability and conductivity.

MATERIALS TODAY (2022)

Article Chemistry, Physical

High-resolution extrusion printing of Ti3C2-based inks for wearable human motion monitoring and electromagnetic interference shielding

Ahmadreza Ghaffarkhah et al.

Summary: This study addresses the challenges of low printing resolution and the inability to create structures with high electrical conductivity and mechanical flexibility in MXene-based printing. By utilizing high-resolution extrusion printing and fabricating composite structures, the researchers were able to expand the applications of MXene-based printing and create highly-sensitive strain sensors. These sensors are capable of monitoring various human activities.

CARBON (2022)

Article Multidisciplinary Sciences

Room-temperature high-precision printing of flexible wireless electronics based on MXene inks

Yuzhou Shao et al.

Summary: This research presents a strategy for direct printing of flexible wireless electronics at room temperature. By regulating the additive-free titanium carbide (Ti3C2Tx) MXene aqueous inks, high-resolution and high-performance functional modules can be fabricated and integrated on various substrates. This work opens up possibilities for high-precision additive manufacturing of printed wireless electronics at room temperature.

NATURE COMMUNICATIONS (2022)

Article Engineering, Environmental

3D printable conductive polymer hydrogels with ultra-high conductivity and superior stretchability for free-standing elastic all-gel supercapacitors

Tao Cheng et al.

Summary: This study presents an effective gelation strategy for the fabrication of high-performance PEDOT:PSS hydrogels with excellent electrical conductivity, mechanical stretchability, and swelling behavior. The resulting hydrogels can be utilized as electrodes for the assembly of substrate-free, highly elastic all-gel supercapacitors with superior energy storage capacity and arbitrary deformability.

CHEMICAL ENGINEERING JOURNAL (2022)

Article Chemistry, Multidisciplinary

Recent advances in conductive polymer hydrogel composites and nanocomposites for flexible electrochemical supercapacitors

Le Li et al.

Summary: Conductive polymer hydrogels have great potential as electrodes and electrolytes for flexible electrochemical supercapacitors. Various chemical and structural designs allow for tuning the properties of conductive polymer hydrogels to match practical demands. Challenges and perspectives for future applications of conductive polymer hydrogel composites and nanocomposites in flexible electrochemical supercapacitors are also discussed.

CHEMICAL COMMUNICATIONS (2021)

Article Materials Science, Multidisciplinary

High-Performance PVA/PEDOT:PSS Hydrogel Electrode for All-Gel-State Flexible Supercapacitors

Qifan Liu et al.

Summary: A hybrid PVA/PEDOT:PSS hydrogel electrode with 3D interpenetrated network structure was successfully prepared, showing excellent mechanical durability and electrochemical performance through the effective combination of interconnectivity and strong intermolecular force. The fabricated supercapacitor maintains a capacitance retention of 98.1% after 1000 bending cycles, with a high energy density and continuous powering ability in various environments, demonstrating great potential for use in the next generation of flexible energy storage devices.

ADVANCED MATERIALS TECHNOLOGIES (2021)

Article Chemistry, Multidisciplinary

Ice-Templated Large-Scale Preparation of Two-Dimensional Sheets of Conjugated Polymers: Thickness-Independent Flexible Supercapacitance

Jie Zhang et al.

Summary: The study focuses on preparing two-dimensional PEDOT:PSS sheets using ice as a template, enhancing mechanical robustness by incorporating WO3 nanowires, and removing the PSS component with concentrated sulfuric acid. The supercapacitor devices prepared exhibit outstanding energy storage characteristics, making it a promising approach for accessing two-dimensional organic sheets.

ACS NANO (2021)

Article Chemistry, Physical

Aqueous MXene/PH1000 Hybrid Inks for Inkjet-Printing Micro-Supercapacitors with Unprecedented Volumetric Capacitance and Modular Self-Powered Microelectronics

Jiaxin Ma et al.

Summary: The water-based printable MXene hybrid ink allows direct inkjet printing of micro-supercapacitors with excellent performance and seamless integration, offering potential for scalable industrialization of self-powered integrated systems. The micro-supercapacitors exhibit impressive volumetric capacitance and energy density, outperforming previously reported inkjet-printed devices.

ADVANCED ENERGY MATERIALS (2021)

Article Chemistry, Multidisciplinary

Aqueous Inks of Pristine Graphene for 3D Printed Microsupercapacitors with High Capacitance

Stefano Tagliaferri et al.

Summary: The fabrication of high-performance microsupercapacitors using 3D printing technology without the need for high temperature processing has achieved exceptional areal capacitance and power density. The rational design of electrode architectures and the use of current collector-free devices have significantly improved electrochemical performance.

ACS NANO (2021)

Article Chemistry, Multidisciplinary

3D Wearable Fabric-Based Micro-Supercapacitors with Ultra-High Areal Capacitance

Dongdong Li et al.

Summary: A novel strategy using 3D fabrics to construct high cross-section micro-supercapacitors is introduced, achieving high areal capacitance and excellent bending stability. The resulting fabric-based MSCs demonstrate ultra-high areal capacitance of 135.4 mF cm(-2) and 94% capacitance retention even after 3000 cycles, showing promise for next-generation wearable electronics.

ADVANCED FUNCTIONAL MATERIALS (2021)

Review Chemistry, Multidisciplinary

3D Printed Micro-Electrochemical Energy Storage Devices: From Design to Integration

Wen Zhang et al.

Summary: This article presents the recent progress in the application of 3D printing technology in micro-electrochemical energy storage devices, highlighting the different 3D printing techniques used for the fabrication of electrodes and other components, and discussing the future research and development direction in this important field.

ADVANCED FUNCTIONAL MATERIALS (2021)

Article Chemistry, Multidisciplinary

A General Crosslinker Strategy to Realize Intrinsic Frozen Resistance of Hydrogels

Dong Zhang et al.

Summary: The study introduces a novel crosslinking strategy to fabricate a series of antifreezing hydrogels with strong antifreezing and mechanical properties in various environments. The hydrogels are proposed to have a general antifreezing property regardless of their network compositions.

ADVANCED MATERIALS (2021)

Article Engineering, Environmental

Flexible, all-hydrogel supercapacitor with self-healing ability

Yongliang Zou et al.

Summary: The study presents an all-hydrogel supercapacitor with high electric conductivity, large specific capacitance, great toughness and self-healing ability. It can maintain stable energy output even after being subjected to various deformations and can self-heal within 4 hours. The supercapacitor is a promising smart storage device for wearable applications.

CHEMICAL ENGINEERING JOURNAL (2021)

Article Chemistry, Multidisciplinary

Wood-Derived, Conductivity and Hierarchical Pore Integrated Thick Electrode Enabling High Areal/Volumetric Energy Density for Hybrid Capacitors

Feng Wang et al.

Summary: This study reported a porous monolithic electrode with high thickness, assembled hierarchically to improve capacitance performance and cycling stability. The electrode maintained 84.5% long-term stability over 10,000 cycles, exhibited exceptional rate capability, and significantly increased energy density.

SMALL (2021)

Article Multidisciplinary Sciences

Thickness-independent scalable high-performance Li-S batteries with high areal sulfur loading via electron-enriched carbon framework

Nana Wang et al.

Summary: By utilizing free-standing and low-tortuosity carbon frameworks as hosts for sulfur and lithium, the authors were able to achieve scalable thickness-independent electrochemical performance.

NATURE COMMUNICATIONS (2021)

Article Chemistry, Applied

Aqueous high-voltage all 3D-printed micro-supercapacitors with ultrahigh areal capacitance and energy density

Yu Liu et al.

Summary: In this study, aqueous planar micro-supercapacitors with ultrahigh areal capacitance and energy density were developed using an efficient all-3D-printing strategy. The printed active carbon/exfoliated graphene electrode ink and electrolyte gel displayed outstanding conductivity, leading to improved shaping and electrochemical performances. The 3D-printed symmetric MSCs showed high stability at a voltage of up to 2.0V, with ultrahigh areal capacitance and exceptional energy density, making them promising for high-power micro-electronics fabrication and integration.

JOURNAL OF ENERGY CHEMISTRY (2021)

Review Physics, Applied

Printed flexible supercapacitor: Ink formulation, printable electrode materials and applications

Jing Liang et al.

Summary: Flexible supercapacitors (FSCs) are attracting attention for their lightweight, easy integration, high power density, fast charge/discharge rate, and safety features. Printed FSC offers an economical solution for manufacturing, relying on functional inks formulation and innovative electrode materials design. The use of inks with excellent rheological properties and advanced electrode materials design are key to the success of next-generation printed FSC with high energy and high power.

APPLIED PHYSICS REVIEWS (2021)

Article Chemistry, Physical

All-3D-printed solid-state microsupercapacitors

Changju Chae et al.

Summary: The miniaturized electrochemical energy storage units have gained significant attention in the field of microelectronic electronics systems with the emergence of the internet of things era. A methodology for fabricating an all-3D-printed solid-state energy storage device was developed, which involves printing 3D-printable highly viscous fluids for metallic current collector, electrode, and electrolyte layers. The printed microsupercapacitor device demonstrates energy density and power density levels approaching the state-of-the-art level for conventional devices.

ENERGY STORAGE MATERIALS (2021)

Article Chemistry, Physical

3D-Printed highly stretchable conducting polymer electrodes for flexible supercapacitors

Jiayu Yang et al.

Summary: This study successfully developed free-standing stretchable electrodes with excellent flexibility and stretchability by designing unique negative Poisson's ratio structures and utilizing 3D printing technology. Additionally, the integration of carbon nanotubes enhanced the electrochemical performance of the electrodes, providing new possibilities for the development of wearable energy storage devices.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

Review Nanoscience & Nanotechnology

Recent Progress in Natural Biopolymers Conductive Hydrogels for Flexible Wearable Sensors and Energy Devices: Materials, Structures, and Performance

Chen Cui et al.

Summary: Natural biopolymer-based conductive hydrogels have shown great potential in wearable and stretchable sensing devices due to their excellent flexibility and conductivity. Biopolymers such as cellulose, chitosan, and silk fibroin are commonly chosen as promising candidates for constructing conductive hydrogels, providing enhanced mechanical properties and remarkable biocompatibility.

ACS APPLIED BIO MATERIALS (2021)

Article Engineering, Environmental

Three-dimensional porous stretchable supercapacitor with wavy structured PEDOT:PSS/graphene electrode

In Kyu Moon et al.

CHEMICAL ENGINEERING JOURNAL (2020)

Review Chemistry, Multidisciplinary

3D Printing for Electrochemical Energy Applications

Michelle P. Browne et al.

CHEMICAL REVIEWS (2020)

Review Polymer Science

PEDOT: Fundamentals and Its Nanocomposites for Energy Storage

Hong-Wu Chen et al.

CHINESE JOURNAL OF POLYMER SCIENCE (2020)

Article Chemistry, Physical

3D-Printed Stretchable Micro-Supercapacitor with Remarkable Areal Performance

Xiran Li et al.

ADVANCED ENERGY MATERIALS (2020)

Article Chemistry, Multidisciplinary

Turning Trash into Treasure: Additive Free MXene Sediment Inks for Screen-Printed Micro-Supercapacitors

Sina Abdolhosseinzadeh et al.

ADVANCED MATERIALS (2020)

Article Multidisciplinary Sciences

3D printing of conducting polymers

Hyunwoo Yuk et al.

NATURE COMMUNICATIONS (2020)

Article Chemistry, Multidisciplinary

Direct Conversion of Fe2O3 to 3D Nanofibrillar PEDOT Microsupercapacitors

Yifan Diao et al.

ADVANCED FUNCTIONAL MATERIALS (2020)

Article Chemistry, Multidisciplinary

Highly Crystalline PEDOT Nanofiber Templated by Highly Crystalline Nanocellulose

Shengyang Zhou et al.

ADVANCED FUNCTIONAL MATERIALS (2020)

Article Multidisciplinary Sciences

Bicontinuous phase separation of lithium-ion battery electrodes for ultrahigh areal loading

Jung Tae Lee et al.

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2020)

Review Engineering, Electrical & Electronic

Recent developments of advanced micro-supercapacitors: design, fabrication and applications

Fan Bu et al.

NPJ FLEXIBLE ELECTRONICS (2020)

Article Multidisciplinary Sciences

Pure PEDOT:PSS hydrogels

Baoyang Lu et al.

NATURE COMMUNICATIONS (2019)

Article Chemistry, Multidisciplinary

3D Printing of Freestanding MXene Architectures for Current-Collector-Free Supercapacitors

Wenji Yang et al.

ADVANCED MATERIALS (2019)

Article Multidisciplinary Sciences

Additive-free MXene inks and direct printing of micro-supercapacitors

Chuanfang (John) Zhang et al.

NATURE COMMUNICATIONS (2019)

Article Chemistry, Physical

Thick Electrode Batteries: Principles, Opportunities, and Challenges

Yudi Kuang et al.

ADVANCED ENERGY MATERIALS (2019)

Article Multidisciplinary Sciences

Conductive carbon nanofiber interpenetrated graphene architecture for ultra-stable sodium ion battery

Mingkai Liu et al.

NATURE COMMUNICATIONS (2019)

Article Chemistry, Physical

3D Printing of Tunable Energy Storage Devices with Both High Areal and Volumetric Energy Densities

Tingting Gao et al.

ADVANCED ENERGY MATERIALS (2019)

Article Chemistry, Physical

MXene/Polymer Hybrid Materials for Flexible AC-Filtering Electrochemical Capacitors

Girish Sambhaji Gund et al.

JOULE (2019)

Article Chemistry, Multidisciplinary

Generalized 3D Printing of Graphene-Based Mixed-Dimensional Hybrid Aerogels

Xingwei Tang et al.

ACS NANO (2018)

Article Chemistry, Multidisciplinary

Development of Graphene Oxide/Polyaniline Inks for High Performance Flexible Microsupercapacitors via Extrusion Printing

Yuqing Liu et al.

ADVANCED FUNCTIONAL MATERIALS (2018)

Article Chemistry, Physical

Full-cell quinone/hydroquinone supercapacitors based on partially reduced graphite oxide and lignin/PEDOT electrodes

Adriana M. Navarro-Suarez et al.

JOURNAL OF MATERIALS CHEMISTRY A (2017)

Article Chemistry, Physical

Semi-Interpenetrating Polymer Networks for Enhanced Supercapacitor Electrodes

Kara D. Fong et al.

ACS ENERGY LETTERS (2017)

Article Chemistry, Multidisciplinary

Rapid and Versatile Photonic Annealing of Graphene Inks for Flexible Printed Electronics

Ethan B. Secor et al.

ADVANCED MATERIALS (2015)

Article Chemistry, Multidisciplinary

Highly Conductive PEDOT: PSS Nanofibrils Induced by Solution-Processed Crystallization

Nara Kim et al.

ADVANCED MATERIALS (2014)