Mechanism analysis of hydroxypropyl guar gum degradation in fracture flowback fluid by homogeneous sono-Fenton process

An effective hybrid system was applied as the first report for the successful treatment of key pollutants (hydroxypropyl guar gum, HPG) in fracturing flowback fluid, and the synergistic index of the hybrid system was 20.45. In this regard, chemical oxygen demand (COD) removal ratio was evaluated with various influencing operating factors including reaction time, H2O2 concentration, Fe2+ concentration, ultrasonic power, initial pH, and temperature. The optimal operating parameters by single-factor analysis method were: the pH of 3.0, the H2O2 concentration of 80 mM, the Fe2+ concentration of 5 mM, the ultrasonic power of 180 W, the ultrasonic frequency of 20-25 kHz, the temperature of 39 celcius, the reaction time of 30 min, and the COD removal rate reached 81.15 %, which was permissible to discharge surface water sources based on the environmental stan-dards. A possible mechanism for HPG degradation and the generation of reactive species was proposed. Results of quenching tests showed that various impacts of the decomposition rate by addition of scavengers had followed the order of EDTA-2Na < BQ < t-BuOH, therefore center dot OH radicals had a dominant role in destructing the HPG. Based on the kinetic study, it was concluded that Chan Kinetic Model was more appropriate to describe the degradation of HPG. Identification of intermediates by GC-MS showed that a wide range of recalcitrant compounds was removed and/or degraded into small molecular compounds effectively after treatment. Under the optimal conditions, the sono-Fenton system was used to treat the fracturing flowback fluid with the initial COD value of 675.21 mg/L, and the COD value decreased to 80.83 mg/L after 60 min treatment, which was in line with the marine sewage discharge standard. In conclusion, sono-Fenton system can be introduced as a successful advanced treatment process for the efficient remediation of fracture flowback fluid.

Automated summary

An effective hybrid system was used to treat hydroxypropyl guar gum (HPG) in fracturing flowback fluid, achieving a COD removal rate of 81.15%. The optimal operating parameters for this system were determined through single-factor analysis, and intermediates were identified by GC-MS analysis. Results showed that the sono-Fenton system successfully reduced the COD value to within the marine sewage discharge standard, making it an efficient remediation process for fracturing flowback fluid.