4.4 Article

Characterization of sputtered nanocrystalline gallium nitride for electron selective contact of crystalline silicon solar cell

Journal

THIN SOLID FILMS
Volume 763, Issue -, Pages -

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.tsf.2022.139582

Keywords

Silicon heterojunction solar cells; Gallium nitride; Sputtering

Funding

  1. JSPS [JP19J23461]
  2. New Energy and Industrial Technology Development Organization (NEDO)
  3. Open Facility Center, Material Analysis Division (Tokyo Tech.)

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This study investigated the properties of sputtered nanocrystalline gallium nitride (nc-GaN) and its potential as an electron selective contact in a silicon heterojunction (SHJ) solar cell. Simulation of the nc-GaN/crystalline silicon (c-Si) heterojunction was performed based on the analysis of deposited nc-GaN films and nc-GaN/c-Si heterojunction devices. The simulation results indicated that using nc-GaN with an electron concentration greater than 5 x 1018 cm-3 and a metal contact with a work function less than 3.9 eV is crucial for obtaining good solar cell performance.
We investigated properties of sputtered nanocrystalline gallium nitride (nc-GaN) to discuss the potential of the nc-GaN as an electron selective contact in a silicon heterojunction (SHJ) solar cell. Modeling of nc-GaN/ crystalline silicon (c-Si) heterojunction was carried out based on the analysis of the deposited nc-GaN films and nc-GaN/c-Si heterojunction devices. The simulation using the developed model well reproduced the current -voltage characteristics of a SHJ solar cell with nc-GaN layer. The device simulation pointed out that it is important to use nc-GaN with electron concentration larger than 5 x 1018 cm-3 and metal contact with work function less than 3.9 eV to obtain good solar cell performance.

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