Journal
SYNLETT
Volume 34, Issue 9, Pages 1042-1048Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/a-2005-5372
Keywords
heteroarenium salts; alcohols; reversible addition; basic conditions
Categories
Ask authors/readers for more resources
The reversible addition of benzyl alcohol onto heteroarenium salts under basic conditions was investigated. By fine-tuning the nature of the arenium and substituents, a range of pyrimidinium substrates capable of undergoing C6-selective alcohol addition was discovered. Crossover experiments were conducted to confirm the addition elimination equilibrium under basic conditions.
The reversible addition of benzyl alcohol onto heteroarenium salts under basic conditions was studied. Fine-tuning of the nature of the arenium and substituents allowed the discovery of a range of pyrimidinium substrates that can undergo C6-selective alcohol addition. Crossover experiments were also performed to confirm the addition elimination equilibrium under basic conditions.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available