Journal
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
Volume 284, Issue -, Pages -Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.saa.2022.121828
Keywords
Oxalyl chloride; BODIPY; Colorimetric; Fluorometric; Sensor
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A novel long wavelength monostyryl BODIPY derivative BDZ-1 was synthesized and successfully used for the high sensitivity and selectivity detection of oxalyl chloride, a highly reactive and harmful chemical. The color and fluorescence changes of BDZ-1 solution allow accurate detection of oxalyl chloride, and the practicability of BDZ-1 was further demonstrated by using a smartphone application for on-site detection.
Herein, a novel long wavelength monostyryl BODIPY derivative (BDZ-1) has been synthesized by rational design and used to detect oxalyl chloride, a highly reactive and harmful chemical to humans and other living organisms, with high sensitivity and selectivity. The purple solution of BDZ-1 changed to pink color immediately upon the addition of oxalyl chloride and the weak red fluorescence changed to strong orange fluorescence simultaneously. In addition, the practicability of BDZ-1 was further explored by using a smartphone application, allowing the sensitive and selective on-site detection of oxalyl chloride.
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