Journal
SOFT MATTER
Volume 19, Issue 5, Pages 1017-1024Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2sm01348g
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The dynamics of long-term phase separation in binary liquid mixtures are studied by tracking the evolution of size, defect, and mesogen alignment in a binary liquid mixture with a confined liquid crystal-rich droplet. Visualizing the liquid crystal droplet configuration through polarisation microscopy, the research compares experimental findings with computational simulations and explains the differences between bulk phases and confined droplets based on the respective thermodynamics of phase separation. The work provides insights into how phase transitions on the microscale deviate from bulk phase diagrams and has relevance to other material systems.
The dynamics of long term phase separation in binary liquid mixtures remains a subject of fundamental interest. Here, we study a binary liquid mixture, where the minority phase is confined to a liquid crystal (LC)-rich droplet, by investigating the evolution of size, defect and mesogen alignment over time. We track the binary liquid mixture evolving towards equilibrium by visualising the configuration of the liquid crystal droplet through polarisation microscopy. We compare our experimental findings with computational simulations and elucidate differences between bulk phases and confined droplets based on the respective thermodynamics of phase separation. Our work provides insights on how phase transitions on the microscale can deviate from bulk phase diagrams with relevance to other material systems, such as the liquid-liquid phase separation of polymer and protein solutions.
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