4.8 Article

Engineering Second-Order Corner States in 2D Multiferroics

Journal

SMALL
Volume 19, Issue 14, Pages -

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/smll.202206574

Keywords

ferroelastic; ferroelectric; second-order topological insulators; zero-dimensional corner states

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The emergence and manipulation of second-order corner states in 2D multiferroic SbAs and BP5 monolayers is demonstrated. Ferroelasticity and ferroelectricity are used to engineer the nontrivial corner states. The corner states appear in the mirror symmetric corners and are perpendicular to the in-plane spontaneous polarization. The spatial distribution of the corner states can be effectively controlled by ferroelastic switching.
The understanding and manipulate of the second-order corner states are central to both fundamental physics and future topotronics applications. Despite the fact that numerous second-order topological insulators (SOTIs) are achieved, the efficient engineering in a given material remains elusive. Here, the emergence of 2D multiferroics SOTIs in SbAs and BP5 monolayers is theoretically demonstrated, and an efficient and straightforward way for engineering the nontrivial corner states by ferroelasticity and ferroelectricity is remarkably proposed. With ferroelectric polarization of SbAs and BP5 monolayers, the nontrivial corner states emerge in the mirror symmetric corners and are perpendicular to orientations of the in-plane spontaneous polarization. And remarkably the spatial distribution of the corner states can be effectively tuned by a ferroelastic switching. At the intermediate states of both ferroelectric and ferroelastic switchings, the corner states disappear. These finding not only combines exotic SOTIs with multiferroics but also pave the way for experimental discovery of 2D tunable SOTIs.

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