Journal
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
Volume 7, Issue 22, Pages 4614-4621Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.jpclett.6b01909
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- Tarbiat Modares University (TMU)
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We have investigated the influence of perovskite morphology on slow and fast charge transport in the perovskite solar cells. Solar cells with different perovskite cuboid sizes (50-300 nm) have been fabricated using various methylammonium iodide concentrations. Both the low-frequency capacitance and hysteresis are maximum for the cell with the largest perovskite grains (300 nm). The low-frequency capacitance is about three orders of magnitude greater than the intermediate frequency capacitance, indicating the great role of ions on the slow responses and hysteresis. The measurement of open circuit voltage decay indicates that for the large grains of 300 nm up to 70% of V-oc remains across the cell, even after passing similar to 40 s. Such a long time V-oc decay demonstrates the large accumulation of the ions at the perovskite interfaces with electron and hole transport layers, which conduct slow redistribution of the charges after the light is turned off.
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