Journal
SCRIPTA MATERIALIA
Volume 222, Issue -, Pages -Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.scriptamat.2022.115030
Keywords
Cu matrix composites; Thermal stability; Activation energy; Mechanical properties
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WC dispersion-reinforced Cu composites with high thermal stability were successfully fabricated using intermittent electrodeposition and spark plasma sintering. The WC nanoparticles were uniformly dispersed in the Cu matrix, impeding grain boundary migration and increasing the grain-growth activation energy. The composite exhibited significantly increased yield strength at high temperatures, making it suitable for use as a heat sink.
WC dispersion-reinforced Cu composites with high thermal stability were fabricated using intermittent elec-trodeposition and the spark plasma sintering (SPS). WC nanoparticles were dispersed uniformly due to the formation of the Cu cladding WC structures. The pin and impurity drag mechanisms contributed by the dispersed WC impeded the migration of grain boundaries. Based on the kinetic analysis, the improved grain-growth activation energy was observed for 3.0 wt% WC-reinforced Cu (up to 376.4 +/- 3.7 kJ/mol), which is over three times higher than that for self-diffusion in pure Cu. The yield strength of this composite increased to 282.9 MPa at 300 degrees C, which is nine times higher than the value in Cu. This work provides an advanced pathway for designing thermal stable Cu composites for application as heat sinks.
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