4.7 Article

Lanthanide-oxo clusters for efficient catalytic reduction of carboxamides

Related references

Note: Only part of the references are listed.
Article Chemistry, Multidisciplinary

Counterintuitive Lanthanide Hydrolysis-Induced Assembly Mechanism

Ming-Hao Du et al.

Summary: The hydrolysis mechanism of lanthanide ions is limited by their elusive coordination configuration and undeveloped technology. By using diketonate ligands, the hydrolyzed intermediate cluster of Ln(3+) can be efficiently stabilized under electrospray ionization conditions. A mass difference fingerprint of isomorphism (MDFI) method allows for the determination of the nuclearity-number of the species without depth resolution. The study provides fundamental insights into the formation, evolution, and assembly of small lanthanide hydroxide units upon hydrolysis.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2022)

Article Chemistry, Inorganic & Nuclear

Deoxygenation of Primary Amides to Amines with Pinacolborane Catalyzed by Ca[N(SiMe3)2]2(THF)2

Chong Yu et al.

Summary: The deoxygenative reduction of amides using pinacolborane (HBpin) in the presence of a catalytic amount of Ca[N(SiMe3)(2)](2)(THF)(2) is an efficient method to access amines, with good tolerance to functional groups and heteroatoms. The proposed reaction mechanism provides insight into this transformation.

ORGANOMETALLICS (2021)

Article Chemistry, Inorganic & Nuclear

Lithium compound catalyzed deoxygenative hydroboration of primary, secondary and tertiary amides

Milan Kumar Bisai et al.

Summary: A selective and efficient method for the deoxygenative reduction of primary to tertiary amides to corresponding amines using pinacolborane (HBpin) and 2,6-di-tert-butyl phenolate lithium center dot THF (1a) as a catalyst has been achieved. Both experimental and DFT studies provide mechanistic insight into the process.

DALTON TRANSACTIONS (2021)

Article Chemistry, Multidisciplinary

La[N(SiMe3)2]3-Catalyzed Deoxygenative Reduction of Amides with Pinacolborane. Scope and Mechanism

Christopher J. Barger et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

Article Chemistry, Organic

Hidden Boron Catalysis: Nucleophile-Promoted Decomposition of HBpin

Andrew D. Bage et al.

ORGANIC LETTERS (2020)

Article Chemistry, Organic

Transition-metal-free catalytic hydroboration reduction of amides to amines

Wubing Yao et al.

ORGANIC CHEMISTRY FRONTIERS (2020)

Article Chemistry, Inorganic & Nuclear

Mild catalytic deoxygenation of amides promoted by thorium metallocene

Sayantani Saha et al.

DALTON TRANSACTIONS (2020)

Article Chemistry, Multidisciplinary

Controlled Reduction of Carboxamides to Alcohols or Amines by Zinc Hydrides

Derek Yiren Ong et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Review Chemistry, Multidisciplinary

Recent Advances in the Metal-Catalyzed Activation of Amide Bonds

Moreshwar B. Chaudhari et al.

CHEMISTRY-AN ASIAN JOURNAL (2019)

Article Chemistry, Multidisciplinary

Frustrated Lewis Pair Catalyzed Hydrogenation of Amides: Halides as Active Lewis Base in the Metal-Free Hydrogen Activation

Nikolai A. Sitte et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

Article Chemistry, Inorganic & Nuclear

Aluminium complex as an efficient catalyst for the chemo-selective reduction of amides to amines

Suman Das et al.

DALTON TRANSACTIONS (2019)

Article Chemistry, Multidisciplinary

Highly selective hydrogenation of amides catalysed by a molybdenum pincer complex: scope and mechanism

Thomas Leischner et al.

CHEMICAL SCIENCE (2019)

Article Chemistry, Multidisciplinary

Mechanistic Insight Facilitates Discovery of a Mild and Efficient Copper-Catalyzed Dehydration of Primary Amides to Nitriles Using Hydrosilanes

Richard Y. Liu et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

Article Chemistry, Organic

Recent Advances in Amide Reductions

Jérôme Blanchet et al.

SYNTHESIS-STUTTGART (2018)

Article Chemistry, Organic

Nickel-Catalyzed Reduction of Secondary and Tertiary Amides

Bryan J. Simmons et al.

ORGANIC LETTERS (2017)

Article Chemistry, Multidisciplinary

Chemoselective Reduction of Tertiary Amides under Thermal Control: Formation of either Aldehydes or Amines

Fredrik Tinnis et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)

Review Chemistry, Multidisciplinary

Main Group Lewis Acid-Mediated Transformations of Transition-Metal Hydride Complexes

Ayan Maity et al.

CHEMICAL REVIEWS (2016)

Review Chemistry, Multidisciplinary

Chemoselective reduction of carboxamides

Atexey Volkov et al.

CHEMICAL SOCIETY REVIEWS (2016)

Article Chemistry, Organic

Mild Metal-Free Hydrosilylation of Secondary Amides to Amines

Pei-Qiang Huang et al.

JOURNAL OF ORGANIC CHEMISTRY (2016)

Article Chemistry, Inorganic & Nuclear

Stable BH3 adducts to rhodium amide bonds

Fabian Mueller et al.

JOURNAL OF ORGANOMETALLIC CHEMISTRY (2016)

Article Chemistry, Physical

Magnesium-Catalyzed Mild Reduction of Tertiary and Secondary Amides to Amines

Nicole L. Lampland et al.

ACS CATALYSIS (2015)

Article Chemistry, Multidisciplinary

Efficient metal-free hydrositylation of tertiary, secondary and primary amides to amines

Enguerrand Blondiaux et al.

CHEMICAL COMMUNICATIONS (2014)

Article Chemistry, Multidisciplinary

Highly Chemoselective Reduction of Amides (Primary, Secondary, Tertiary) to Alcohols using SmI2/Amine/H2O under Mild Conditions

Michal Szostak et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)

Article Chemistry, Applied

A Practical Procedure for Reduction of Primary, Secondary and Tertiary Amides to Amines

Jonathan T. Reeves et al.

ADVANCED SYNTHESIS & CATALYSIS (2013)

Article Chemistry, Multidisciplinary

Two Iron Catalysts are Better than One: A General and Convenient Reduction of Aromatic and Aliphatic Primary Amides

Shoubhik Das et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2012)

Article Chemistry, Inorganic & Nuclear

Calcium-mediated hydroboration of alkenes: Trojan horse or true catalysis?

Sjoerd Harder et al.

JOURNAL OF ORGANOMETALLIC CHEMISTRY (2012)

Article Chemistry, Multidisciplinary

Iridium-Catalyzed Reduction of Secondary Amides to Secondary Amines and Imines by Diethylsilane

Chen Cheng et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2012)

Article Chemistry, Multidisciplinary

New catalyst systems for iron-catalyzed hydrosilane reduction of carboxamides

Hironori Tsutsumi et al.

CHEMICAL COMMUNICATIONS (2011)

Article Chemistry, Multidisciplinary

Zinc-Catalyzed Reduction of Amides: Unprecedented Selectivity and Functional Group Tolerance

Shoubhik Das et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2010)

Article Chemistry, Multidisciplinary

Direct Hydrogenation of Amides to Alcohols and Amines under Mild Conditions

Ekambaram Balaraman et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2010)

Article Chemistry, Multidisciplinary

Hydrosilane Reduction of Tertiary Carboxamides by Iron Carbonyl Catalysts

Yusuke Sunada et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2009)

Article Chemistry, Organic

Rhodium-catalyzed hydroboration reactions with sulfur and nitrogen analogues of catecholborane

Siphamandla W. Hadebe et al.

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY (2006)