Journal
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
Volume 7, Issue 24, Pages 4988-4995Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.jpclett.6b02063
Keywords
-
Categories
Funding
- IISER Pune
- DST NanoMission (India) [SR/NM/NS-42]
- DAE-BRNS (India) [2011/20/37C/17/BRNS]
- SERB [SB/FTP/PS-032/2014, SB/S2/CMP-048/2013]
- Swedish Research Council (VR)
- Swedish National Infrastructure for Computing (SNIC)
- CSIR (India)
Ask authors/readers for more resources
Owing to long spin-relaxation time and chemically customizable physical properties, molecule-based semiconductor materials like metal-phthalocyanines offer promising alternatives to conventional dilute magnetic semiconductors/oxides (DMSs/ DMOs) to achieve room-temperature (RT) ferromagnetism. However, air-stable molecule based materials exhibiting both semiconductivity and magnetic-order at RT have so far remained elusive. We present here the concept of supramolecular arrangement to accomplish possibly RT ferromagnetism. Specifically, we observe a clear hysteresis-loop (H-c approximate to 120 Oe) at 300 K in the magnetization versus field (M H) plot of the self-assembled ensembles of diamagnetic Zn-phthalocyanine having peripheral F atoms (ZnFPc; S = 0) and paramagnetic Fe-phthalocyanine having peripehral H atoms (FePc; S = 1). Tauc plot of the self-assembled FePc center dot center dot center dot ZnFPc ensembles showed an optical band gap of similar to 1.05 eV and temperature-dependent current-voltage (I-V) studies suggest semiconducting characteristics in the material. Using DFT+U quantum-chemical calculations, we reveal the origin of such unusual ferromagnetic exchange-interaction in the supramolecular FePc center dot center dot center dot ZnFPc system.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available