Stretch-orientation-induced reduction of friction in well-entangled bidisperse blends: a dual slip-link simulation study

We investigated the rheological properties of bidisperse entangled-polymer blends under high-deformation-rate flows by slip-link simulations with a friction reduction mechanism. The friction reduction mechanism induced by the stretch and orientation (SORF) is important to predict the viscoelasticity under uniaxial elongational flows. To test the applicability of this mechanism for bidisperse systems, we incorporated an expression of friction reduction (Yaoita et al. Macromolecules 45:2773-2782 2012) into the Doi-Takimoto slip-link model (DT model) (Doi and Takimoto Philos Trans R Soc Lond A 361:641-652 2003). For six experimental bidisperse systems, i.e., four polystyrene blends and two polyisoprene blends, the extended DT model where the order parameter of the friction reduction mechanism is evaluated through the component averages succeeds in reproducing the data under uniaxial elongation and shear. This success is due to the suppression of the stretch of the longer chains using the statistical average over each component. Through this study, the SORF expression improves the rheological prediction for bidisperse entangled polymer melts under uniaxial elongational flows with strain rates comparable to or larger than the inverse of the Rouse relaxation time of the longer chains. Additionally, the predictions with the SORF using the component average for the stretches reproduce the steady viscosities because under elongational flows, the states of the components with different molecular weights clearly differ from each other depending on their Rouse relaxation time. The finding means that for chain dynamics, the friction coefficient is determined by the state of the surrounding polymer chains and the state of the chain.

Automated summary

This study investigated the rheological properties of bidisperse entangled-polymer blends under high-deformation-rate flows using slip-link simulations and a friction reduction mechanism. The incorporation of the friction reduction expression into the Doi-Takimoto slip-link model successfully predicted the data for six experimental bidisperse systems. By statistically averaging the components, the stretch of the longer chains was suppressed, improving the rheological prediction under high elongation rates.